核磁共振方法研究煤吸附过程.pdf

International Journal of Coal Geology 131 (2014) 32–40 Contents lists available at ScienceDirect International Journal of Coal Geology journal homepage: /locate/ij coa lgeo Quantitative characterization of methane adsorption on coal using a low-field NMR relaxation method Yanbin Yao ⁎, Dameng Liu, Songbin Xie Beijing Key Laboratory of Unconventional Natural Gas Geology Evaluation and Development Engineering, China University of Geosciences, Beijing 100083, PR China a r t i c l e i n f o a b s t r a c t Article history: To develop a nuclear magnetic resonance (NMR) method for characterizing the methane adsorption capacity of Received 8 March 2014 coals, we built an NMR transparent isotherm adsorption experimental setup. Proton (1H) NMR measurements Received in revised form 27 May 2014 were first performed with bulk methane to obtain a hydrogen amplitude index reflecting the methane volume Accepted 2 June 2014 concentration. Then, dry coals were pressurized with methane to assess the quantity of adsorbed methane at Available online 8 June 2014 pressures up to 6.1 MPa. The adsorption isotherms obtained by this procedure were compared with the corre- Keywords: sponding sorption isotherms determined by the traditional volumetric method under the same experimental Coal adsorption capacity conditions. The methane transverse relaxation time (T2 ) spectra have three distinct peaks at T2 b 7 ms, T2 = Volumetric method