锂离子电池负极碳基复合材料的分析-化学工程与技术专业毕业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - PAGE VI- -III- -III- Abstract The hard carbon was coated with pitch pyrolitic carbon to improve first coulombic efficiency and reversible capacity in the thesis. In order to improve the first coulombic efficiency and reversible capacity of hard carbon,The pyrolytic process of pitch was researched and used to prepared the twice coated pitch/hard carbon composite. Acetylene black was also researched to find the influence on first coulombic efficiency of hard carbon-based composite. At the same time,the preparation method of graphene was also researched,to improve the electrochemical performance,the si/graphene and si@c/graphene composite was prepared by high-temperature method. The pitch pyrolitic carbon prepared by stytle 2 method showed the highest first coulombic efficiency of 71.9%,which is hiher than the efficiency of hard carbon(65.0%); the pyrolitic carbon prepared by stytle 4 showed the highest reversible capacity,the first reversible capacity was 251mAh·g-1,after 50 cycle it was dcreased to 246mAh·g-1 with the capacity retention ratio of 98%.then the pitch/hard carbon composite coated twice showed the high first co ulombic efficiency of 72.2% ,high reversible capacity of 252mAh·g-1，and high capacity retention ratio of 97.2% after 30cycles. Silicon/hard carbon composite prepared by ball-milling showed perfect performance while the mass ratio of silicon/hard carbon was 1/8.the composite showed high first coulombic efficiency of 72.3% and high reversible capacity of 361 mAh·g-1,the reversible capacity remaining was 240 mAh·g-1 after 50 cycles and the capacity retention ratio was 66.5%,the influence on the first coulombic efficecy of acetylene black was also researched,it showed that the first irreversible coulombic efficiency contributed by acetylene black was about 6.7%. Graphene was prepared by high temperature method,it showed good electrochemical performance and relatively thin shee