湿法炼锌二次置换后液脱除铊的研究陶杰12许斌12孔金换12商.DOC

doi： doi：10.3969/j.issn.1007-7545.2019.05.002 陶杰1,2，许斌1,2，孔金换1,2，商绘峰1,2，董高峰1,2，杨腾蛟1,2，田磊2,3 （1.河南豫光锌业有限公司，河南 济源 454650； 2.河南豫光金铅集团有限责任公司，河南 济源 454650； 3.江西理工大学，江西 赣州 341000） 摘要：针对工业上硫酸锌溶液二次置换后液中铊的分布特征，采用锌粉置换、锌粉+活性炭、锌粉+高锰酸钾、锌粉+乙酸铅等方法脱除二次置换后液中的铊。结果表明，反应温度70 ℃、高锰酸钾用量3 g、锌粉加入量40 g、搅拌转速300 r/min、反应时间90 min的条件下，锌粉+高锰酸钾联合法可以脱除85.83%的铊。在反应温度90 ℃、乙酸铅用量0.8 g、锌粉加入量40 g、搅拌转速300 r/min、反应时间90 min的条件下，锌粉+乙酸铅联合法可以脱除93.89%的铊。结合工业生产实际，建议采用锌粉+乙酸铅联合法脱除二次置换后液中的铊。 关键词：湿法炼锌；二次置换后液；高锰酸钾；乙酸铅；Tl；脱除率 中图分类号：TF813 文献标志码：A 文章编号：1007-7545（2019）05-0000-00 Study on Removal of Thallium from Secondary Displacement Solution of Zinc Hydrometallurgy TAO Jie1,2, XU Bin1,2, KONG Jin-huan1,2, SHANG Hui-feng1,2, DONG Gao-feng1,2, YANG Teng-jiao1,2, TIAN Lei2,3 (1. Henan Yuguang Zinc Industry Co., Ltd., Jiyuan 454650, Henan, China; 2. Henan Yuguang Gold and Lead Group Co., Ltd., Jiyuan 454650, Henan, China; 3. Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China) Abstract：Based on distribution characteristics of thallium in secondary replacement solution of zinc sulphate solution in industry, thallium was removed from this solution by zinc powder replacement, zinc powder + activated carbon, zinc powder + potassium permanganate, and zinc powder + lead acetate, respectively. The results show that Tl removal rate of zinc powder + potassium permanganate is 85.83% under the optimum conditions including reaction temperature of 70 ℃, potassium permanganate dosage of 3 g, zinc powder dosage of 40 g, stirring speed of 300 r/min, and reaction time of 90 min. Removal rate of Tl of zinc powder + lead acetate is 93.89% under the optimum conditions including reaction temperature of 90 ℃, lead acetate dosage of 0.8 g, zinc powder dosage of 40 g, stirring speed of 300 r/min, and reaction time of 90 min. Combined with actual industrial production, it is recommended to remove thallium from secondary replacement solution by zinc powder + lead acetate. Key words：zinc hydrometallurgy; secondary repla