辽河常压渣油中含氮化合物悬浮床加氢转化规律研究-化学工程与技术专业论文.docx

辽河常压渣油中含氮化合物悬浮床加氢过程转化规律研究 辽河常压渣油中含氮化合物悬浮床加氢过程转化规律研究 侯婷(化学工程与技术) 指导教师：刘东教授 摘 要 本论文主要对辽河常压渣油中含氮化合物的类型与分布进行研究并对分散型催化 剂存在下辽河常压渣油悬浮床加氢产物中的含氮化合物进行分析。通过对比反应前后的 含氮化合物的类型与分布的差异，考察辽河常压渣油在悬浮床加氢反应过程中含氮化合 物的转化规律。 应用傅罩叶离子回旋共振质谱(FT-ICR MS)对加氢反应前后辽河常压渣油及其窄 馏分分析表明，辽河常压渣油中的含氮化合物主要是Nl类化合物，以中度缩合度物质 为主。随着沸点升高含氮化合物的不饱和度逐渐增大，并逐渐出现NlOl、N102类等含 多种杂原子的含氮化合物。其中轻蜡油中含氮化合物也主要为Nl类，其等效双键值 (DBE)介于4．15；重蜡油中含氮化合物也主要为Nl类，但N101、N102类物质相对丰 度有所增加。辽河常渣加氢裂化反应产物中氮化合物仍主要为Nl类为主，DBE值范围 介于4．1 5的Nl类物质存在于所有馏分中，随沸点升高含氮化合物缩合度逐渐增加，仅 有少量N2类物质出现在减压渣油中。 通过酸萃取法和柱层析色谱法分别分离出了反应前后辽河常压渣油及其各馏分的 碱性和非碱性含氮化合物组分，并进行了FT-IR和GC—MS研究，研究发现随着沸点升高 辽河常压渣油中碱性含氮含化合物含量逐渐减少，非碱性含氮化合物含量逐渐增加。其 中碱性含氮化合物以喹啉类物质为主，而非碱性含氮化合物组分以咔唑类、胺类为主， 从加氢裂化反应前后碱性及非碱性含氮化合物的分布来看，认为在加氢裂化反应过程中 部分非碱性含氮化合物向碱性含氮化合物发生了转化，部分含氮化合物发生了断侧链、 缩合和加氢饱和反应，使氮杂环化合物减少，部分NlOl类化合物转化为Nl类化合物。 关键词：含氮化合物，转化，高分辨质谱，悬浮床加氢 Study Study on the transformation of nitrogen compounds in Liaohe atmospheric residue during slurry—bed hydrocracking Hou Ting(Chemical Engineering and Technology) Directed by Professor Liu Dong Abstract In this papeL group composition and distribution of nitrogen compounds in the Liahe atmospheric residue and in its slurry-bed hydrocracking product were mainly studied．It aimed to identify the transformation regularity of nitrogen compound during the slurry phase hydrocracking and compare the di fferences between the feed oil and product． The Liahe atmospheric residue and fractions were characterized by FT-ICR MS to find out the main nitrogen compounds in LHAR were N1 class(e．g．，molecules containing the same numbers of N，O and S atoms)．With the degreeofunsaturation and boiling point increasing，NlOi and N102 class gradually appeared．The main nitrogen compounds in light VGO were also Nl class and their DBE values were between 4 and 1 5．The Nl class was still the main nitrogen compound in heavy VGO，but the contents of N l O l，N l 02 class were increased．The nitrogen compound in LHAR slurry—bed hydrocracking product mainly was NI class．The N1 class which DBE values was between