负热膨胀反钙钛矿锰氮化合物的研究综述.pdfVIP

47 11 Vol.47 No.11 2011 11 1362—1371 ACTA METALLURGICA SINICA Nov. 2011 pp.1362–1371 ∗ (, 100124) Æ , . , , . , , , TF777.1 A 0412−1961(2011)11−1362−10 REVIEW IN ANTIPEROVSKITE MANGANESE NITRIDES WITH NEGATIVE THERMAL EXPANSION PROPERTIES SONG Xiaoyan, SUN Zhonghua College of Materials Science and Engineering, Key Lab of Advanced Functional Materials, Education Ministry of China, Beijing University of Technology, Beijing 100124 Correspondent: SONG Xiaoyan, professor, Tel: (010 E-mail: xysong@bjut.edu.cn Supported by National Basic Researh Program of China (No.2011CB612207) and Beijing Natural Science Foundation (No.2112006) Manuscript received 2011–06–20, in revised form 2011–08–01 ABSTRACT Antiperovskite manganese nitrides are a group of negative thermal expansion (NTE) materials that have been developed rapidly in recent years. They exhibit important potential applica- tions due to isotropic NTE property, controllable coefficient of NTE and NTE operation temperature window, and good metallic and mechanical properties. In this review, state of the arts and recent development in the field of studying antiperovskite manganese nitrides have been summarized and commented, which consist of introduction of history, classification, preparation approaches, influencing factors and mechanisms of NTE for such materials. The prospects are also described for antiperovskite manganese nitrides. KEY WORDS negative thermal expansion, zero thermal expansion, antiperovskite structure, manganese nitride Æ , [1] Æ . Æ