乳品中硫氰酸盐的来源及其风险分析.PDFVIP

※专题论述 Journal of Dairy Science and Technology 2013, Vol.36 No.4 36 乳品中硫氰酸盐的来源及其风险分析 刘 园，邹 洁* (江苏省产品质量监督检验研究院，江苏 南京 210007) 摘  要：硫氰酸盐曾作为生鲜奶的保鲜剂被广泛使用，但因其毒性，已被我国列为乳及乳制品中的非法添加 物质。鉴于硫氰酸盐的毒性作用，我们对市售乳品的硫氰酸盐含量进行风险监测，并对乳品中硫氰酸盐可能 对人类健康造成的危害进行风险分析，结果发现852个监测样品中的硫氰酸含量均小于10mg/k g ，其中25 .9 % 样品的硫氰酸根含量低于1mg/kg ，仅有6 .24 % 的样品含量在5 ～10mg/kg之间。由此，我们分析了乳品中硫氰 酸盐的可能来源，认为852个市售乳制品中的硫氰酸盐主要来源于动物生鲜乳的自身本底，系非法添加的可能 性极低。 关键词：乳品；硫氰酸盐；来源；风险分析 Origins and Risk Assessment of Thiocyanate in Dairy Products * LIU Yuan ，ZOU Jie (Jiangsu Product Quality Testing and Inspection Institute, Nanj ing 210007, China) Abstract ：The lactoperoxidase–thiocyanate–hydrogen peroxide system is widely used as a feasible method for temporary preservation of raw milk in China. Nevertheless, due to its toxic and harmful nature, thiocyanate has been listed as an illegal food additive in raw milk and dairy products. In this study, various amounts of thiocyanate less than 10 mg/kg were found in 852 samples of dairy products marketed in China, of which 25.9% were less than 1 mg/kg and only 6.24% were 5– 10 mg/kg. Furthermore, our analysis showed that the possible origin of thiocyanate might be raw milk but not illegal addition. Finally a risk assessment was performed on its potential health hazards. Key words ：dairy products；thiocyanate ；origins；risk assessment 中图分类号：TS252.7 文献标志码：A 文章编号：1671-5187(2013)04-0036-03 - 1 乳品中硫氰酸钠的使用概况 硫氰酸盐是硫氰酸根离子SCN 所成的盐，常见的包括 无色的硫氰酸钾、硫氰酸钠、硫氰酸铵和硫氰酸汞，主要 作为化工原料用于农药、医药、印染、电镀等行业。除此 乳品中添加硫氰酸盐主要是起防腐保鲜作用。199 1 之外，硫氰酸盐(一般是硫氰酸钠)还可与过氧化氢合用， 年，W H O 和F A O 的食品法典