锂离子电池负极材料-碳化钙骨架碳的制备及改性研究物理化学专业论文.docxVIP

湘潭大学硕士学位论文 湘潭大学硕士学位论文 II II Abstract Carbide derived carbon is an amorphous porous material, it has many advantages: low cost, narrow pore size distribution, large specific surface area, controlled pore size distribution and friendly to environment etc. Carbide derived carbon has played an increasingly important role in many areas such as gas-storage, carbon coating in tribology and supercapacitor. In this paper, we firstly used carbide derived carbon as anode material and studied its electrochemical performances. We modified CCDC with LiOH, Li2CO3 and H2O2, in order to improve its electrochemical performances. Firstly , CCDC was synthesized from CaC2 in a freshly chlorine which was prepared by manganese dioxide and strong hydrochloric acid in the temperature rang of 400 ℃~700 ℃. The results showed that CCDCs were amorphous nanoscaled materials. The specific surface area decreased from 658 m2/g to 201 m2/g and the average pore size increased from 3.766 nm to 3.842 nm with reaction temperature increasing from 400 ℃ to 700 ℃. The first charge specific capacity of CCDC prepared at 600 ℃ was 335.4 mAh/g, the charge capacities was 266.8 mAh/g after 30 cycles at 0.1 C. In order to reduce the irreversible capacity and improve electrochemical performance of CCDC, CCDC/Li composites were synthesized by using lithium hydroxide (LiOH) and lithium carbonate (Li2CO3) as lithium sources, and the effects of lithium content on the structures and electrochemical performances of CCDC / Li were investigated. The results indicated that addition of lithium did not change the structures of CCDC, but reduced the irreversible capacities and improved the electrochemical performances of CCDC. Compared with the pure CCDC, CCDC / LiOH and CCDC/Li2CO3 had higher capacities, better cycle performances and reversibility. The first charge specific capacity of CCDC/LiOH composite with 4 wt.% LiOH was 350.9 mAh/g and keeped 266.7 mAh/g after 50 cycles at 0.5 C, the corresponding capacity retention r