稀土镧改性磷钨杂多酸盐催化油酸与甲醇酯化反应合成生物柴油活性.doc

PAGE 4 稀土镧改性磷钨杂多酸盐催化油酸与甲醇酯化反应合成生物柴油活性研究 舒庆*基金项目：国家自然科学基金资助项目21466013 *基金项目：国家自然科学基金资助项目21466013)；江西省2014年度自然科学青年基金重大项目(20143ACB21018) 作者简介：舒 庆(1979- )，男，博士，副教授，主要从事能源化工、催化反应工程和反应器设计方面的研究工作， E-mail address: shuqing@tsinghua.org.cn. （江西理工大学冶金与化学工程学院，江西 赣州 34100） 摘要：以H3PW12O40和La(NO3)3为原料，通过离子交换法制备了一种稀土镧改性磷钨杂多酸盐催化剂.通过扫描电镜、红外光谱和X射线粉末衍射等表征方法，对合成的催化剂的物理及化学性能进行了分析，进而通过以油酸和甲醇为反应物的酯化反应，对其催化活性进行了研究.结果表明：稀土镧已经导入了磷钨杂多酸的骨架结构，并与杂原子P形成了配位键，有效提高了磷钨杂多酸的比表面积和孔径；合成的催化剂具有完整的Keggin型结构；当反应温度为62°C，油酸与甲醇摩尔比为1:6，反应时间为4.5 h，催化剂用量为反应物质量的2.5 %，油酸的转化率可达88.0 %. 关键词：；稀土；镧；杂多酸盐；酯化反应；生物柴油 中图分类号: TQ 645. 8 　　　　　　　文献标识码: A Studies on the Catalytic Activity of La-Modified Phosphotungstic Heteropoly Acid Salt in the Synthesis of Biodiesel from the Esterification of Methanol and Oleci Acid SHU Qing, HOU Xiao-peng, LIU Feng-sheng, TANG Guo-qiang, XU Bao-quan, Zhang Cai-xia (School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China) Abstract: La-modified phosphotungstic heteropoly acid salt catalyst was prepared from the using of H3PW12O40 and La(NO3)3 as raw materials through the ion exchange method. The physical and chemical properties of the obtained-catalyst were analyzed with the employing of scanning electron microscopy, infrared spectroscopy and X-ray powder diffraction. The catalytic activity of the obtained-catalyst was studied from the employing of it in the esterification reaction with the oleic acid and methanol as raw materials. Results had shown that the rare earth lanthanum has been introduced into the skeleton structure of phosphotungstic heteropoly acid and formed new coordination bond with the heteroatom P, which has effectively improved the specific surface area and pore size of phosphorus tungsten heteropoly acid; La-modified phosphotungstic heteropoly acid salt keeps the Keggin structure of phosphotungstic heteropoly acid completely; A yield of oleic acid methyl ester 88.0 % was obtained when the