红外-喇曼光谱-公开课件.pptVIP

喇曼位移的计算光谱分析 The Raman-shift can approximately be described by the following formula: ???????????????????????????????????????????????????????? k = measure for the strength of the bound ? = reduced mass. This simple formula illustrates the effect of the mass of the atoms of a particular covalent bound and the strength of that bound on the Raman-shift. For example: substitution of an atom by its radio-active analogue will not change the strength of that bound, however the reduced mass will differ significantly. As a result the Raman frequency will shift towards lower wavenumbers. Another exa