云南文山某难选硫化铜矿的浮选试验研究.doc

PAGE PAGE 7 *收稿日期：2015-11-20 基金项目：国家自然科学基金项目；云南省教育厅科学研究基金项目(2013Y323) 作者简介：蒋京航(1992-)，男，硕士研究生，研究方向，为稀有金属选冶理论与工艺。 云南东川某低品位难选硫化铜矿的浮选回收 蒋京航1,2，叶国华1,2*，张世民1,2，张爽2，林佩佳2 （1.省部共建复杂有色金属资源清洁利用国家重点实验室,云南 昆明 650093；2.昆明理工大学国土资源工程学院,云南 昆明 650093） 摘 要：云南东川某铜矿含Cu 0.65%，其中次生硫化铜占有率达85.6%，铜氧化率9.6%；矿石中黄铁矿含量较高，铜硫分离难度较大，并含有较多的易泥化脉石矿物，属低品位难选硫化铜矿。针对该矿石的性质特点，对其进行了浮选回收研究，结果表明：以CaO作pH值调整剂和铜硫分离时的抑制剂、Na2SiO3作分散剂和抑制剂，磨矿细度选择80%-74um较为合适，Na2S用量600g/t时可达到较好的沉淀、分散与活化效果，捕收剂优选为PAC，其最佳用量为120g/t。在最佳条件下，采用“一粗-二精-二扫”的闭路流程，获得了较好的技术指标，最终精矿Cu品位和回收率分别达20.12%和90.39%。 关键词：硫化铜矿；浮选；回收；磨矿细度；铜硫分离 Ddoi:10.3969/j.issn.1000-6532.2016.04x.00x 中图分类号：TD952 文献标志码：A 文章编号:1000-6532(2016)04-00 Recovery of a Low-grade Refractory Copper Sulfide Ore by Flotation in Dongchuan, Yunnan province JIANG Jinghang1,2, YE Guohua1,2*, ZHANG Shimin1,2, ZHANG Shuang 2,LIN Peijia (1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization，Kunming 650093, China； 2．Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China) Abstract: A certain copper ore in Dongchuan, Yunnan province, with the copper content of only 0.65%, the distribution rate of secondary copper sulfide reaching as high as 85.6% and the copper oxidation rate of 9.6%, having the high content of pyrite which could lead to a difficulty in copper-sulfur separation, containing some easily-sliming gangue minerals, belongs to the low-grade refractory copper sulfide ore. Flotation recovery study based on the ore’s properties shows that, grinding fineness is more appropriate to be chose as 80%-74um, Na2S, at the mount 600g/t, has the better multi-function including precipitation, dispersion and activation, PAC should be chose as collector with optimal amount of 120g/t when CaO is chose as pH regulator and depressant of copper-sulfur separation, meanwhile, Na2SiO3 is used as depressant and dispersant. Finally, by adopting the closed-circuit flowsheet of “one roughing - two cleaning - t