镁钙系材料烧结性能研究-材料科学与工程专业论文.docxVIP

AbstractIn Abstract In the present work，calcination and sinterability of mixed Mg(OH)2一magnesite and Ca(OH)2-magnesite powders were investigated by using magnesite and CaO (Chemical agent)as staring materials，and characterized by means XRD，TG—DSC， FSEM and FactSage thermodynamic simulation．The results show that： “Decomposition—carbonization-decarbonization’’reactions of Mg(OH)2 in the Mg(OH)2-MgC03 powders and Ca(OH)2 in the Ca(OH)2一MgC03 powders during calcinations is proved most important to prevent MgO in calcined powder from agglomerating and to improve sinterability of the calcined powders．High homogeneous particle structure in calcined Mg(OH)2··MgC03 and Ca(OH)2--MgC03 powders were achieved and high density of 3．089／cm3 and 3．349／ema were reached in MgO and MgO-CaO clinkers，including 20％MgO and 30％CaO in starting materials， respectively,after sintering at 1 650。C X 3h in the present work． Grinding treatment of the calcined Mg(OH)2·-MgC03 and Ca(OH)2·-MgC03 powders improved sinterability of both calcined powders．Bulk density of the MgO and MgO-CaO clinkers，which calcined powders including 20％MgO and 30％CaO in starting materials were ball milled for 30min．．reached 3．16 g／cm3 and 3．40 g／cm3 respectively after sintering at 1 650℃for 3h． Keywords：Mg(OH)2；Ca(OH)2；magnesite；decomposition；MgO-CaO clinker； sinterability lI 万方数据 目 目 录 摘 要 I Abstract ． ．．．．．．．．．．．． ．．．．．．．．．．． ．．． ． ．．． ．． ．．． ．． ．．．．．．．．．．． ． ． ． ．． ． II 第一章文献综述 1 1．1菱镁矿概述 1 1．1．1菱镁矿的化学成分和矿物组成 1 1．1．2菱镁矿晶体结构 ．1 1．1．3菱镁矿的物理化学性质 2 1．1．4烧结镁砂研究进展 ．2 1．2镁钙砂研究进展 4 1．2．1镁钙砂概述 ．4 1．2．2镁钙砂的生产 ．7 1．2．3镁钙系耐火材料的应用 8 1．2．4镁钙系耐火材料抗水化性能的改善 8 1．3选题意义及研究内容 ．．1l 第二章试验研究方案及研究方法 ．12 2．1试验用原料 ．12 2．2试验设备 ．14 2．3试验研究方案及研究内容 ．14 2．4分析表征及性能检测 ．14 第三章Mg(OH)2．菱镁矿混合粉体的轻烧热分解进程及烧结性能研究 16 3．1试验配比 ．16 3．2试验过程 ．16 3．3试验结果与讨论 ．17 3．3．1 Mg(OH)2．菱镁矿混合粉体轻烧热分解 17 3．3．2 Mg(OH)2．菱镁矿轻烧粉体烧结性能 24 3．4本章小结 ．29 第四章Ca(OH)2．菱镁矿混合粉体的轻烧热分解进程及烧结性能研究 ．3 1 4．1试验配比 ．3 1 4．2试验过程 ．3 1 4．3试验结果与讨论 ．32 III 万方数据 4．3．1 4．3．1 Ca(OH)2．菱镁矿混合粉体