HZSM-5上异丁烯直接胺化反应制备叔丁胺的分析.pdfVIP

HZSM．5上异丁烯直接胺化反应制备叔丁胺的研究 aboutdirectaminationof to on Study isobutylenetert-butylamine HZSM．5 Abstract raw and Asall chemicalmaterial pharmaceutical importantorganic are methodsto suchas intermediates，theremany preparetert-butylaminehydrolysis of of or N—tert—butylacetamide tea—butylurea，hydrolysis aminationof aminationof aminationof haloalkane，directtert—butanol，directmethyl tert aminationof directaminationof ether,direct butyl isobutylene，etc．．Therein，the to hasobtained of attentions，becausehigh isobutylenetert-butylaminemany prepare sieve atom andenvironmental molecular efficient economy friendlyprocess．Zeolite is usedas in oftheacidnatureandordered reactions，because widely catalystsmany Air andChemicalsInc．and structureofzeolites．AmericanProduct microporous GermanBASFbothfoundthat and zeolites(ZSM一5 good indirectaminafionof catalyticperformance isobutylene． on Tofuther theeffectofzeolitesandreactionconditions study isobuty’lene of