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1、Ambient Temperature HYDROLYsis of CARBONYL SULFIDE Using γ-Alumina CATALYsts: Effect of Calcination Temperature and Alkali Dopingγ
【题目】使用γ-氧化铝的羰基硫的室温水解:煅烧温度和碱掺入的作用【作者】 Thomas, Barry; Williams, B. Peter; Young, Nicola; Rhodes, Colin; Hutchings, Graham J.(Department of Chemistry, Cardiff UniversityCardiff CF10 3TB, UK)【来源】CATALYsis Letters, 86(4), 201-205 (English) 2003 Kluwer Academic/Plenum Publishers. CATALYsis Letters 86 4 201-205 English 2003 CALEER 1011-372X 【摘要】 The hydrolysis of COS using .gamma.-alumina as catalyst at 20 .degree.C is described and discussed. In particular, the effect of calcination on the catalyst activity is investigated. Catalysts calcined at 100 and 500 .degree.C are found to give the highest catalyst activities, in terms of both specific (mol COS converted/g catalyst/h) and intrinsic (mol COS converted/m2 catalyst/h) activity. Calcination at other temps. leads to diminished catalyst activity. The effects are discussed in terms of the known surface chem. of .gamma.-alumina involving physisorbed water, surface dehydroxylation and defect formation. The addn. of alkali additives (Li+, Na+, K+, Cs+, Mg2+, Ca2+, Ba2+, Si2+) is also reported. Only K+ and Cs+ give a sustained enhancement in catalyst activity, whereas all the other additives act as catalyst poisons for the steady-state performance measured following 5 h time-onstream. Interestingly, addn. of Na
2、Low temperature HYDROLYsis of CARBONYL SULFIDE using .gamma.-alumina CATALYsts.
【题目】使用γ-氧化铝催化剂的羰基硫的低温水解【作者】 West, John; Williams, B. Peter; Young, Nicola; Rhodes, Colin; Hutchings, Graham J.(Department of Chemistry, Cardiff UniversityCardiff CF10 3TB, UK)【来源】 Catal. Lett., 74(3-4), 111-114 (English) 2001 Kluwer Academic/Plenum Publishers. Catal. Lett. 74 3-4 111-114 English 2001 CALEER 1011-372X 【摘要】 The HYDROLYsis of COS using alumina as CATALYst in the temp. range 10-80.degree.C is descr
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