超快光学-第14章-超快光谱.pptVIP

Heterodyned ultrafast polarization spectroscopy of CS2 Loughnane, et al., Ultrafast Phenomena X, p. 304 (1996). OHD-RIKES study of CS2 at different temperatures. Temporally and spectrally resolving the fluorescence of an excited molecule Exciting a molecule and watching its fluorescence reveals much about its potential surfaces. Ideally, one would measure the time-resolved spectrum, equivalent to its intensity and phase vs. time (or frequency). Here, excitation occurs to a predissociative state, but other situations are just as interesting. Analogous studies can be performed in absorption. Tim