活性炭去除水中四氯化碳的影响因素试验研究.docVIP

 活性炭去除水中四氯化碳的影响因素试 验研究 张满满 1，肖昕 1，朱雪强 1，谭敏 2 （1. 江苏省资源环境信息工程重点实验室，中国矿业大学环境与测绘学院，江苏徐州 221116；2. 环河海大学境学院，南京 210098） 摘要：活性炭具有较好的吸附特性和再生性，可以作为一种高效的吸附材料，而四氯化碳 (CCL4)具有性质稳定、难以自然降解的特点，因此可以利用活性炭的强吸附性去除四氯化碳。 通过批量化试验研究了活性炭对四氯化碳的去除特性及影响因素。结果表明：(1) 四氯化碳 的去除效果随着活性炭投加量的增加而增大，活性炭与四氯化碳溶液的接触面积越大，吸附 效果越好。(2) 活性炭粒径越小，对四氯化碳的吸附效果越好。然而当活性炭投加量达到某 一值之后，四氯化碳去除率增幅不太明显。(3) 随着吸附时间的推延，活性炭对四氯化碳的 吸附去除效果增加，但速率却随之减小。(4) 酸性条件下活性炭对四氯化碳的去除效率较高， 但 pH 对四氯化碳的吸附影响作用不是太大，不是活性炭对四氯化碳吸附的主导性影响因子。 关键词：四氯化碳；活性炭；吸附；去除率 中图分类号：X592 文献标识码：A The influence factors of adsorption of ccl4 in water by active carbon Zhang Manman1, Xiao Xin1, Zhu Xueqiang1, Tan Min2 (1. Jiangsu Provincial Key Laboratory of Resources and Environmental Information System,School of Environmental Science and Spatial Informatics,China University of Mine and Technology, Xuzhou Jiangsu 221116; 2. College of Environment, Hehai University，Nanjing Jiangsu 210098) Abstract: Active carbon is a kind of high efficient adsorption material with good adsorption and reproducibility. Carbon tetrachloride has been characterized by stable properties and difficult to be degraded, so active carbon absorption method was used in the treatment of removing the carbon tetrachloride. The removal rate of carbon tetrachloride and influence factors were investigated in this paper. The results showed that: (1) The removal efficiency of carbon tetrachloride increases with the adding of dosage of active carbon and contact area between carbon tetrachloride and active carbon. (2) The adsorption efficiency increases with the decrease of particle size of active carbon. When dosage of active carbon up to a certain value, it has few influence on the removal efficiency. (3) With the increment of adsorption time, the removal efficiency is increased, but the rate is reduced. (4) Under the acidic condition the removal efficiency is increased. pH has few influence on the adsorption efficiency, and it is not belong to the dominant influencing factors. Key words: carbon tetrachloride