糖蜜淀粉发酵味精处理废母液生产硫酸铵工艺研究.pdf

甘蔗糖业 2011 年第 3 期，2011 年 6 月 Sugarcane and Canesugar, No. 3, Jun. 2011 糖蜜淀粉发酵味精处理废母液生产硫酸铵工艺研究 1 2 1 李锦荣 ，吴海锋 ，谭文兴 1 2 （广州甘蔗糖业研究所 广东省甘蔗改良与生物炼制重点实验室，广东广州 510316 ； 广州奥桑味精食品有限公司, 广东广州 510280 ） 摘 要：味精发酵液经冷冻等电点法提取谷氨酸后排放的母液具有 COD 高、BOD 高、硫酸根含量高以 及 pH 值低的特点，每生产 1 t 味精，大约要排出 5 t 提取谷氨酸后的母液。通过浓缩，采用连续结晶方 法，严格控制 pH 、真空、密度、液位、温度，通过两级调控、两级结晶而制造出高产量高质量的硫酸 铵肥料，含氮量≥19%(干基计) ，回收率达到 50% ～55% （以发酵总酸计），取得一定的环境效益和经济 效益。 关键词：发酵；母液；结晶；硫酸铵 中图分类号：X792 文献标识码：A 文章编号：1005-9695(2011)03-0034-04 MSG Waste Liquor from the Starch Molasses Fermentation Process to Produce Ammonium Sulfate 1 2 1 LI Jin-rong , WU Hai-feng , TAN Wen-xing 1 ( Guangzhou Sugarcane Industry Research Institute/Guangdong Key Lab of Sugarcane Improvement Biorefinery, Guangzhou 510316; 2MSG Food Co., Ltd. Guangzhou Aosang, Guangzhou 510280) Abstract: Monosodium glutamate (MSG) broth by extraction of frozen glutamate isoelectric point of the mother liquor after the discharge has a feature characterized by its high COD, BOD, high sulfate content and low pH values. To produce 1 ton of MSG, about 5 tons of liquor after the extraction of glutamic acid will be discharged. In this paper, concentrated, continuous crystallization method was employed, strict control of pH, vacuum, density, level, temperature was conducted via two control and two-stage crystallization to produce high yields of high-quality ammonium sulfate fertilizer with nitrogen content ≥ 19% (dry basis Dollars), and the recovery rate was 50%～55% (of total