经丁二酮肟修饰的改性皂土对废水中镍的吸附-中国环境科学.pdf

中国环境科学 2009,29(7) ：713~717 China Environmental Science 经丁二酮肟修饰的改性皂土对废水中镍的吸附 * 张 东 ,宋恩军,张丽丽,任广军 (沈阳理工大学环境与化学工程学院, 辽宁 沈阳 110168) 摘要：采用十六烷基三甲基溴化铵(CTMAB)对皂土改性,用丁二酮肟(DMG)对其表面修饰,并制备了新型固态吸附剂.研究了该吸附剂对水 中 Ni2+ 的吸附行为.结果表明,该固态吸附剂对水中 Ni2+具有较强的吸附能力.吸附量受介质 pH 值、温度和吸附时间的影响.其吸附行为符 合 Langmuir 吸附等温模型和 HO 准二级动力学方程,吸附焓变(△H)为 58.759kJ/mol,各温度下,吸附自由能变(△G)均＜0,熵变(△S)均＞0, 该吸附反应为吸热的自发过程.吸附了 Ni2+ 的丁二酮肟修饰改性皂土,可用 0.1mol/L 的 HNO3 溶液洗脱再生. 关键词：丁二酮肟(DMG) ；修饰；改性皂土；镍；吸附行为；电镀废水 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2009)07-0713-05 * Modified organobentonite with DMG adsorb for nickel ion in wasterwater. ZHANG Dong , SONG En-jun, ZHANG Li-li, REN Guang-jun (School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang 110168, China). China Environmental Science, 2009,29(7)：713~717 Abstract ：A sort of cheap sorbent was prepared through modifying organobentonite with dimethylglyoxime (DMG). The adsorption behavior of the modified organobentonite with DMG for nickel ion in water was investigated. The nickel ion in water could be adsorbed on the DMG modified organobentonite. The adsorption quantity was affected by the pH value of medium, temperature and time. The adsorption behavior followed Langmuir adsorption isotherm and pseudo-second-order kinetic model. The enthalpy changes (△H) of the adsorption process was 58.759 kJ/mol. At various temperatures, Gibbs free energy changes (△G) were negative, and entropy changes (△S) were positive. The reaction of adsorption was an endothermal and spontaneous process. The nickel ion adsorbed on the sorbent could be completely eluated by using 0.1mol/L HNO3. Key words ：dimethylglyoxime (DMG) ；modification ；organobentonite ；nickel ；adsorption behavior ；electroplating