304 L不銹鋼軋延組織之氫脆特性研究.pptVIP

彎曲試片於腐蝕環境中時間與總裂縫長度曲線圖 腐蝕環境：室溫之H2S水溶液及80℃之NaCl鹽霧試驗 304L不銹鋼經輥軋後，沃斯田鐵會應變誘發麻田散鐵相變態，且會在兩ε-martensite的交會點上形成α`-martensite，而常溫輥軋試片之α`-martensite含量較多加熱滾軋之試片多，且敏化處理後，部份α`-martensite及ε-martensite會回復成沃斯田鐵。 輥軋後之試片由於表面加工硬化或麻田散鐵相變化的程度較高的緣故，造成材料表面平均硬度較心部高，且CW試片內部生成α`-martensite最多，故表面及心部硬度差異最大。 結果與討論 H2S水溶液中之缺口拉伸試驗，304L不銹鋼由於麻田散鐵相為氫捕集處，使氫不易擴散至裂縫，故輥軋試片之NTS loss值較低，經敏化後部分麻田散鐵會回復成沃斯田鐵，減少氫捕集區，造成NTS loss值增加。 於H2S水溶液中之缺口拉伸試驗，當拉伸速率下降時，材料之氫脆敏感性增加，造成破斷面平坦區分部比例升高、二次裂縫出現機率增加。 常溫輥軋後之試片，易受氫脆影響而產生平行裂縫成長方向之二次裂縫，經過敏化後，其平坦脆性區減少、延性特徵增加；加熱滾軋之試片，受氫脆影響而產生沿晶界成長之二次裂縫，尤以敏化後之試片最為明顯。 * ? 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries. The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION. * * ? 2007 Microsoft Corporation. All rights reserved. Microsoft, Windows, Windows Vista and other product names are or may be registered trademarks and/or trademarks in the U.S. and/or other countries. The information herein is for informational purposes only and represents the current view of Microsoft Corporation as of the date of this presentation. Because Microsoft must respond to changing market conditions, it should not be interpreted to be a commitment on the part of Microsoft, and Microsoft cannot guarantee the accuracy of any information provided after the date of this presentation. MICROSOFT MAKES NO WARRANTIES, EXPRESS, IMPLIED OR STATUTORY, AS TO THE INFORMATION IN THIS PRESENTATION. * * ? 2007 Microsoft Corporation.