Pathways and kinetics of partial oxidation of phenol in supercritical water外文学习材料.pdfVIP

Chemical Engineering Journal 175 (2011) 201–206 Contents lists available at SciVerse ScienceDirect Chemical Engineering Journal j o u r na l h o me p ag e: w w w. elsev /locate/cej Pathways and kinetics of partial oxidation of phenol in supercritical water Qingqing Guan a,b,c , Chaohai Wei a,b,c,∗ , Xin-Sheng Chai d a College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, China b The Key Lab of Pollution control and Ecosystem restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, China c The Key Laboratory of Environmental Protection and Eco-Remediation of Guangdong Regular Higher Education Institutions, South China University of Technology, Guangzhou 510006, China d State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510006, China a r t i c l e i n f o a b s t r a c t Article history: This study reports on the pathways and kinetics of individual gaseous species involved in the partial Received 30 May 2011 oxidation of phenol in supercritical water. The pathway is a combination of supercritical water oxidation Received in revised form (SCWO) and supercritical water gasification (SCWG) processes. A kinetic model that involves oxygen is 19 September 2011 proposed that fits the experimental data and accurately predicts the effects of the O/phenol ratio on the Accepted 21 September 2011 decomposition of phenol. Specifically, at lower O/Phenol ratios, t