共沉淀法制备黄色荧光粉.docVIP

共沉淀法制备黄色荧光粉 及其性能研究 学生姓名：朱晓晶 学 号：310706010531 指导教师：关荣峰 专 业：材料科学与工程 年 级：2007级 学 校：河南理工大学 摘要 TOC \o 1-3 \h \z \u 白光发光二极管(LED)被公认是21世纪最有价值的新型绿色照明光源，在不久的将来将取代白炽灯和日光灯成为照明市场的主导。目前商用白光LED大部分采用光转换方式，将YAG荧光粉涂敷在蓝光LED芯片表面，由蓝光激发荧光粉发出黄光，经混合成白光。作为核心技术的荧光粉在发光器件中发挥着重要作用，对荧光粉的研究变得尤为重要。为了满足不同照明环境要求，需要生产不同色坐标和色温的光源，这需要调节YAG：Ce荧光粉的射波长，而稀土掺杂是一种有效的改变YAG：Ce发射波长的方法。 本论文用共沉淀法制备YAG：Ce荧光粉，研究了YAG相形成温度，探讨了稀土掺杂对荧光粉结构和发光性能的影响，主要研究内容及结论如下： （1）用共沉淀法制备出了各项性能优异的荧光粉样品，在烧结温度达到900℃时，样品的图谱呈现很好的YAG相。实验表明：当煅烧温度为900℃时，，样品即能够形成纯的YAG相。 （2）YAG荧光粉样品经过光色电综合性能测试，使荧光粉发光性能最好的Ce最佳掺量为x=0.06。 （3）为了改善荧光粉普遍存在显色指数不高的问题，通过掺杂Gd、La两种稀土离子，解决色坐标偏离白光中心这一问题。本文通过加入Gd、La两种稀土离子，能够引起荧光粉发射光谱的红移或增加了光谱中的红光成分。 关键词：发光；YAG；荧光粉；LED Abstract White light-emitting diode (LED) is recognized as the most valuable green light source in the 21st century. In the near future it will replace incandescent and fluorescent lighting to become dominant of the light market. At present the majority of the commercial white LED use light conversion method. As the YAG phosphor coating on the surface of blue LED chips, blue light excites the phosphor, which issued a yellow phosphor. Then the two light mix into white light. As the core technology, the phosphor plays an important role in the light-emitting devices. So the study of phosphors becomes particularly important To meet the requirements of the different lighting conditions,. We need to produce different color coordinates and color temperature of light source, it needs to produce different radio wavelengths of YAG:Ce phosphor ,and rare earth doping is an effective method to change YAG: Ce emission wavelength .In this study，YAG: Ce phosphor is prepared by coprecipitation , we researched the formation temperature of YAG phase ,discussed the effect on the structure and luminescent properties of the phosphor by doping rare earth , Main contents and conclusions are as follows: The phosphor samples with excellent performance were made by coprecipitation. With the sintering