载银壳聚糖的固色机理及其处理染色薄木性能的研究-北京林业大学学报.pdf

第37卷摇 第6期 北 京 林 业 大 学 学 报 Vol.37,No.6 2015年6月 JOURNAL OF BEIJING FORESTRY UNIVERSITY Jun. ,2015 鄄鄄 DOI:10.13332/ j.1000 1522 载银壳聚糖的固色机理及其处理染色薄木性能的研究 张摇 颖摇 于志明摇 张摇 扬摇 唐睿琳 (北京林业大学木质材料科学与应用教育部重点实验室) 摘要:通过分析pH值对CTS鄄Ag与酸性染料反应产物的性能影响,揭示CTS鄄Ag 的固色机理。 采用不同抗菌染色工 艺制备抗菌染色薄木,分析其颜色、耐水性、耐光性以及防霉抗菌性能。 结果表明:CTS鄄Ag与酸性染料能在酸性条 件下发生酸碱中和反应,酸性越强,染料的上染率越高,固色效果越好;抗菌染色薄木与直接染色薄木之间的色差, 工艺B工艺C工艺A;抗菌染色薄木的水洗色牢度,工艺C工艺A工艺B;工艺A制取的抗菌染色薄木的日 晒色牢度变差,工艺B、C制取的抗菌染色薄木的日晒色牢度得到改善;抗菌染色薄木的抗菌防霉性能,工艺A工 艺C工艺B。 关键词:载银壳聚糖;抗菌;染色;固色机理;薄木 鄄鄄 鄄鄄 鄄鄄 中图分类号:S784摇 摇 文献标志码:A摇 摇 文章编号:1000 1522(2015)06 0107 05 ZHANGYing;YUZhi鄄ming;ZHANGYang;TANG Rui鄄lin.Color fixation mechanism of CTS鄄Ag and its effect on the properties of dyed veneer.Journal of Beijing Forestry University (2015)37(6) 107鄄鄄 111 [Ch,10 ref.] MOE Key Laboratory of Wooden Material Science and Application,Beijing Forestry University,Beijing,100083,P. R. China. We analyzed the effect of pH value on the properties of reaction productsbetween CTS鄄Ag and acid dyes in order to optimize the processes of antibacterial dyeing veneers and reveal the color fixation mechanism of CTS鄄Ag. The chromatic aberration, water fastness, light fastness, and antibacterial property of antibacterial dyedveneerswith variousprocesseswere measured. Theresultsshowedthat:an acid鄄base neutralization reaction occurred between CTS鄄Ag and acid dyes under acid condition,and the lower pH value,the higher value of dye uptake rate and better fixing effect. Chromatic aberration value between CTS鄄Ag鄄treated antibacterial dyed veneer (ADV) and untreated ADV ranked as: ADV