Influence of Impurities in Electrolyte (Tin, Germanium, and Antimony) on Current Efficiency within Electrowinning of Zinc 电解质(锡、锗、锑)中杂质对锌电积电流效率的影响.pdf
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ISSN Russian Journal of NonFerrous Metals, 2014, Vol. 55, No. 4, pp. 327–330. © Allerton Press, Inc., 2014.
Original Russian Text © V.M. Alkatsev, M.I. Alkatsev, V.A. Lin’kov, I.V. Darchiev, 20 14, published in Izvestiya VUZ. Tsvetnaya Metallurgiya, 2014, No. 3, pp. 20–24.
METALLURGY
OF NONFERROUS METALS
Influence of Impurities in Electrolyte (Tin, Germanium,
and Antimony) on Current Efficiency within Electrowinning of Zinc
V. M. Alkatsev, M. I. Alkatsev, V. A. Lin’kov, and I. V. Darchiev
NorthCaucasian Mining and Metallurgical Institute (State Technical University), Vladikavkaz, Russia
email: mikchail@list.ru
Abstract—This article discusses the effect of tin, germanium, and antimony, as well as animal glue, on cur
rent efficiency η and specific power consumption ( W) within the electrowinning of zinc. Adequate regression
models of η and W as a function of cathode current density, concentrations of impurities, and animal glue in
electrolyte at a constant temperature have been obtained. The ranks of independent variables in terms of
intensity of influence on η has been determined. They are located in the cluster as follows (in decreasing
order): Ge, Sn, and Sb. It has been established experimentally that antimony in the concentration range
0.001–0.150 mg/L increases the current efficiency within the electrowinning of zinc.
Keywords: zinc electrowinning, current efficiency, specific power consumption, mathematical statistics
DOI: 10.3103/S1067821214040026
INTRODUCTION with diameters of 0.1–1.0 mm uniformly distributed
Soviet zinc plants faced the strong negative influ throughout the cath
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