生命与材料—生命自组装.pptVIP

From Nature to Biomimics Bio-inspired Surface With Special Wettability Why lotus leaves have self-cleaning ability? Why mosquito eyes have antifogging functionality? Why water striders can walk on the water??? Chem.Soc.Rev.,2010,39, 3240–3255 Adv. Mater. 2007 10 1002 Nature 2004, 432, 36 Structure of these biological organisms What’s the relationship between multiscale structures and special wettability? A: Young’s mode： cosθ=(γsv-γsl)/γlv, θ is contact angle B: Wenzel’s mode： γlv cosθW=r(γsv-γsl) , r is the surface roughness factor cosθW = rcosθ C: Cassie’s mode： cos θC=fs cosθs+fv cosθv Fundamental theories——contact angle(CA) Progress in Materials Science 58 (n2013) 503–564 For the Wenzel’s mode, when θ90°, θW θ; θ90°, θW θ. Roughness can amplify the contact effect. Fundamental theories—— sliding angle(SA) α SA (α) is the slant angle that a liquid droplet begins to slide down an inclined plate. A larger CA and a smaller SA lead to easier slide of liquid droplets. Cassie’s mode is more favorable for slide of liquid droplets. Increasing surface roughness can lower sliding angle. Low adhesion superhydrophobic Self-cleaning of Lotus leaves Antifogging of mosquito eyes Air layer exists between multi- scale structured surface and water Large CA Small SA Water striders can walk on the water Arrangement and orientation of micro- and nanostructures Anisotropic adhesion superhydrophobic Explanation to the special property of the biological organisms superhydrophobic materials Design the micro/ nanometer structures Choose lower surface energy material hemispheres/Ag nanoparticles composite arrays Cu(OH)2 ribbed nanoneedle arrays silicon hollow-tip arrays PS films with similar petal structures VCu-NO3/VCo-Al-CO3= 3:1-chitosan hybrid film Al2O3/PMMA lamellar composites Nano Today (2011)6, 155—175 Application of superhydrophobic surfaces Thank you! 2014-5-31