温湿度对不同吸湿剂吸湿特性及动力学模型影响.docxVIP

温湿度对不同吸湿剂吸湿特性及动力学模型影响赵亚，石启龙，王相友，王娟（山东理工大学农业工程与 温湿度对不同吸湿剂吸湿特性及动力学模型影响 赵亚，石启龙，王相友，王娟 （山东理工大学农业工程与食品科学学院，山东淄博 255049） 摘要：采用静态吸附法研究了无水氯化钙、六偏磷酸钠、山梨糖醇、魔芋葡甘聚糖、壳聚糖、活性氧化铝粉和膨润土等 7 种吸 湿剂在不同温度（2、10、18 ℃）和相对湿度 RH（76%、86%、96%）下放置 15 d 时的吸湿特性。结果表明，温度一定时，吸湿量 随 RH 升高而增加；RH 一定时，吸湿量随温度变化略有差异。采用 Weibull 模型拟合吸湿量数据，得到吸湿动力学参数 M∞和 β，通 过线性回归得到 M∞和温湿度的关系。除山梨糖醇外，Weibull 模型与吸湿量拟合精度较高。M∞较高的吸湿剂为无水氯化钙（1.117~2.137 g H2O/g）、六偏磷酸钠（0.297~0.856 g H2O/g）和山梨糖醇（0.083~38.567 g H2O/g），其 β 值范围为：无水氯化钙（25.5~119.8 h）、六 偏磷酸钠（91.2~290.0 h）和山梨糖醇（1.1~185.6 h）。壳聚糖和膨润土的 M∞受温度、RH 的共同影响，而六偏磷酸钠和山梨糖醇的 M∞ 仅受 RH 的影响。研究结果可为双孢蘑菇 MA 贮藏期间 RH 控制提供理论依据。 关键词：温度；相对湿度；吸湿剂；动力学模型 文章篇号：1673-9078(2014)12-158-163 DOI: 10.13982/j.mfst.1673-9078.2014.12.027 Effect of Temperature and Relative Humidity on Absorption Characteristics and Kinetic Models of Different Absorbent ZHAO Ya, SHI Qi-long, WANG Xiang-you, WANG Juan (School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255049, China) Abstract: The static adsorption method was employed to investigate the moisture absorption characteristics of seven different moisture absorbents, including calcium chloride (CaCl2), sodium hexametaphosphate, sorbitol, konjac glucomannan (KGM), chitosan, activated aluminum oxide powder, and bentonite, which were exposed to different temperatures (2 ℃, 10 ℃, and 18 ℃) and relative humidities (RHs) (76%, 86%, and 96%) for 15 days. The results showed that moisture absorption for the same absorbent increased with increasing RH at a fixed temperature, while moisture absorption varied for different absorbents with elevated temperature at a fixed RH. The Weibull model was used to fit the experimental moisture content data; the model parameters of M∞ and β were obtained, and the relationship between M∞ and temperature/humidity was established using linear regression analysis. Except for sorbitol, the accuracy of fit of the moisture content data to the Weibull model was high. The moisture absorbents with high holding c