片状石墨与球状石墨铸铁的高温氧化.pdfVIP

片狀石墨與球狀石墨鑄鐵的高溫氧化 防蝕工程　第二十五卷第四期　第187 ~ 194 頁　2011 年 12 月 Journal of Chinese Corrosion Engineering, Vol. 25, No. 4, pp. 187 ~ 194 (2011) 林盟斌、王朝正* High Temperature Oxidation of Flake and Spheroidal Graphite Cast Irons M. B. Lin, C. J. Wang* Received 10 August 2010; received in revised form 7 December 2010; accepted 28 March 2011 選用片狀石墨鑄鐵(FC200)與球狀石墨鑄鐵(FCD400)為試驗材料，分析 400 ~ 750 °C 靜滯空氣氧化動力學，探討石墨型態對鑄鐵抗高溫氧化性能的影響。低碳鋼(SB450)為對照 組材料，比較兩種鑄鐵材料與低碳鋼之高溫氧化。實驗結果顯示石墨型態對於鑄鐵材料抗 高溫氧化性有明顯的影響。片狀石墨鑄鐵之抗高溫氧化性低於球狀石墨鑄鐵。觀察片狀石 墨鑄鐵高溫氧化層的連續成長行為顯示，由於氧氣持續由片狀石墨晶界滲入，促使鐵氧化 物沿片狀石墨晶界持續快速生長，氧化層往內側生長增厚，因此片狀石墨鑄鐵氧化速率常 數高出球狀石墨鑄鐵氧化速率常數 5 倍，而球狀石墨鑄鐵高溫氧化速率常數與低碳鋼相當 接近。根據以上高溫氧化動力學與氧化層成長行為分析結果，片狀石墨對鑄鐵材料抗高溫 氧化能力有明顯的負面影響，而球狀石墨對鑄鐵之抗高溫氧化性則無明顯的影響。 關鍵詞：片狀石墨鑄鐵；球狀石墨鑄鐵 ；高溫氧化。 ABSTRACT Flake and spheroidal graphite cast irons with a similar composition were subjected to high temperature oxidation, and the effects of graphite morphology and distribution on the oxidation behavior of the cast irons were investigated. High temperature oxidation tests were performed at temperatures between 400 and 750 °C in air. For comparative purposes, low carbon steel was also tested. Graphite morphology significantly affected the high-temperature oxidation resistance of the cast irons. The flake graphite cast iron exhibited a worse high-temperature oxidation resistance than the spheroidal graphite cast iron. Since the graphite flakes acted as suitable sites for