《高固含革用基层水性聚氨酯的合成及性能研究》【毕业设计论文】.docVIP

PAGE 毕 业 论 文 （2011届） 题 目 高固含革用基层水性聚氨酯的合成及性能研究 二○一一年六月 高固含革用基层水性聚氨酯的合成及性能研究 摘 要：以PTHF(聚四氢呋喃二醇)、721(聚己二酸乙二醇酯)和IPDI(异佛尔酮二异氰酸酯)等为主要原料，采用预聚体分散法和丙酮法相结合的方法合成了性能良好的高固含水性聚氨酯（WPU），并在此基础上进行有机硅改性，以提高它的耐水性、透气性，满足在皮革基层上应用的要求。 实验考察了改性前不同种类NCO单体、NCO/OH摩尔比、不同种类羟基单体以及改性后有机硅加料方式、有机硅加量、扩链剂含量等工艺条件对乳液和成膜性能的影响。通过红外光谱(IR)对改性前后WPU结构进行表征，同时也对改性前后WPU进行拉伸强度、表面接触角、热重进行了分析测试，并作了相关讨论。 结果表明：721、PTHF摩尔比为2：1，NCO/OH摩尔比为1.2：1，磺酸型扩链剂含量为0.46%，有机硅KH550含量为0.88%时，能得到固含55.00%、白色略泛蓝、稳定性好、耐水性好的WPU乳液，与工厂样品性能基本相符，满足在皮革基层上应用的要求。 关键词：水性聚氨酯； 高固含； 改性； 耐水性 Synthesis and properties of high solid waterborne polyurethane used in the leather grassroots. Abstract： Based on PTHF(PTMEG),721(polyethylene glycol adipate) and IPDI(isoflurane ketone diisocyanate) as the main raw material,the high performance and high solid WPU was synthesized by prepolymer dispersion and acetone method. Its capability of water resistance and air permeability was greatly enhanced by using silicone as modifier so that it can meet the requirements to be used in the leather grassroots. The processing conditions which can influence the quality of WPU emulsion and film were studied in this paper, such as different types of NCO monomer, the molar ratio of NCO/OH, different types of OH monomer before modification with silicone .After modification with silicone ,the way of adding silicone , the amount of silicone and the amount of chain extender were also investigated. The structure of the product before and after adding silicone were characterized and compared by The Fourier Transform Infrared (FTIR). Tensile strength, contact angle and TGA were also tested and discussed in this paper. The results show that when the 721/PTHF mole ratio is 2，the NCO/OH mole ratio is 1.2，the content of sulfonated chain extender is about 0.46％ and the content of silicone is about 0.88％, white with a little blue, good stability, good capability of water resistance WPU emulsion whose solid content is 55.00% can be synthesized.The high