硅溶胶-辛基三乙氧基硅烷杂化材料对水泥基材料性能的影响研究.docVIP

青岛理工大学本科学位论文 PAGE PAGE I 硅溶胶-辛基三乙氧基硅烷杂化材料对水泥基材料性能的影响研究 摘要 水泥基复合材料是世界范围主要的工程材料，而混凝土是建筑行业的主导材料。随着混凝土的广泛运用，其耐久性问题逐渐成为限制其发展的主要问题。而造成其耐久性不足的主要原因是混凝土对水、氯离子等的抗侵蚀性低，如果这种情况得不到控制将会给生产建设带来巨大的经济损失。因此，在易发生侵蚀的环境中，混凝土材料的防水措施就变的十分重要。现今，内掺和表面涂刷防水材料是延长水泥基材料的使用寿命，提高其耐久性的一条有效途径。 本课题研究了使用硅溶胶-辛基三乙氧基杂化液表面处理和内掺处理的水泥基材料的防水性。试验选用了不同杂化比例的杂化液对混凝土进行表面处理，对水泥净浆和水泥砂浆进行内掺处理。混凝土的水灰比为0.4和0.5。经过处理后，测试了混凝土的吸水率和抗氯离子侵蚀、水泥净浆和砂浆的强度、28d水泥砂浆的吸水率。分析不同处理对水泥基材料性能和吸水的影响规律。 经过试验研究表明内掺硅溶胶-辛基三乙氧基杂化液的水泥净浆和砂浆的强度，在杂化液内掺量为2%时强度都能增强大约6%，杂化液内掺为5%时强度都下降大约8%，28天水泥砂浆的防水效果也比较明显，吸水率最大能降低35.9%。外涂硅溶胶-辛基三乙氧基杂化液可以有效的降低混凝土的吸水量，吸水量降低了一倍以上，氯离子扩散系数能降低21.16%。 关键词：硅溶胶；有机硅；杂化材料；表面处理；抗氯离子 PAGE PAGE II Abstract Cement base composite material is the world leading engineering materials, and concrete is the dominant material of the construction industry。With the extensive use of concrete, the durability problems gradually become the main problems limiting its development. Caused by the insufficient durability of concrete in water, is the leading cause of the erosion resistance of chloride ion and so on low, if this situation is not controlled will brings the huge economic losses to the production and construction。In prone to erosion environment, therefore, concrete material waterproof measures becomes very important. With surface coating waterproof material within today, is to extend the service life of cement base material, and an effective way to improve the durability of it. This topic is studied to use silicon sol - octyl triethoxy hybrid liquid surface treatment and the mixing process of cement base material waterproof. Test chose different hybridization percentage of hybrid liquid surface treatments on concrete, net of cement slurry and cement mortar in mineral processing. Concrete water cement ratio of 0.4 and 0.5. After processing, test the concrete of water absorption and resistance to chloride ion erosion, 28 d of net cement slurry and cement mortar strength, bibulous rate of cement mortar. Analysis of different