《熔融法制备可降解聚酯PBAT蒙脱土纳米复合材料及其性能表征》-毕业设计（论文）.docVIP

XX 大 学 毕 业 论 文 题 目：熔融法制备可降解聚酯PBAT/蒙脱土 纳米复合材料及其性能表征 学 号： X 姓 名： X 年 级： X 学 院： 材料与化工 系 别： 化工 专 业： 化学工程与工艺 指导教师： X 完成日期： X 熔融法制备可降解聚酯PBAT/蒙脱土纳米复合材料及其性能表征 PAGE IV 熔融法制备可降解聚酯PBAT/蒙脱土纳米复合材料及其性能表征 PAGE IV 摘 要 本论文以可降解聚酯聚对苯二甲酸丁二醇酯-己二酸丁二醇酯(PBAT)、有机蒙脱土（OMMT）为原料，采用熔融插层复合技术制备可降解聚酯(PBAT)/有机蒙脱土纳米复合材料，并对材料的相关性能进行了表征和研究。 首先，采用固相插层法以十六烷基三甲基溴化铵（CTAB）为插层剂，对蒙脱土进行有机化处理，并对固相插层工艺进行了详细的研究。结果表明：插层剂用量、搅拌温度，搅拌时间都成为了影响插层效果的因素。然后将有机蒙脱土（OMMT）与PBAT进行熔融插层共混，制得可降解聚酯PBAT/蒙脱土纳米复合材料，并使用X射线衍射(XRD)、拉伸机、差示量热扫描(DSC)对其性能进行表征。考察了蒙脱土含量对复合材料性能的影响。结果表明，熔融插层制备的纳米复合材料的力学性能、热性能等与纯的PBAT相比都有了较大的提高。 关键词：固相法；蒙脱土；对苯二甲酸丁二醇酯-己二酸丁二醇酯；熔融插层；纳米复合材料 Abstract Based on the raw material of degradable polyesteramides (PBAT) and organic montmorillonoid (OMMT), this paper explores the process of that using melting intercalation composite technology to produce degradable polyesteramides (PBAT) / organic montmorillonoid nanocomposite materials. Meanwhile, it also studies the preperites of the namocomposites. Firstly, using solid-phase intercalation and taking cetyltrimethylammonium bromide (CTAB) as intercalator, This production makes an organic treatment to montmorillonoid and explores the technology of solid-phase intercalation in detail. The results show that the content of CTAB, stirring temperature and stirring time can influence MMT layer basing space obviously. Afterwards, organic montmorillonoid (OMMT) and degradable polyesteramides (PBAT) are mixed with melting intercalation technology and produce the degradable polyesteramides (PBAT) / montmorillonoid nanocomposite material. And the properties of nanocomposites are characterized using XRD, tensile tester and DSC. The influence of MMT content on properties of nanocomposites is studied in detail. It is found that the properties of nanocomposites are improved largely than that of pure PBAT. Key words: solid-phase intercalation; montmorillonoid;