热力学第三定律规定熵低温热力学备课讲稿.pptVIP

Other scientists joined the campaign for low temperatures, notably Charles Saint Ange Thilorier (1771–1833), a chemist, who liquefied carbon dioxide in a strong metallic boomerang under high pressures and then lowered the pressure – hence, by evaporation, the temperature – far enough to make it solid. When enough solid was accumulated to experiment with, it turned out that carbon dioxide at 1atm goes immediately from the solid phase into vapour and vice-versa – at –78.5°C – in a process called sublimation, or de-sublimation respectively. That makes solid carbon dioxide popular as dry ice. It