金属氟化物对LiAlH4吸放氢性能和机制影响的研究-毕业论文(设计).docVIP

金属氟化物对LiAlH4吸放氢性能和机制影响的研究 摘　要 众所周知，在整个氢能的应用系统中，储氢技术是最关键的环节，因此高性能储氢材料的研发是氢能安全高效应用的前提。本文通过机械球磨的方法制备了LiAlH4–10 %MgF2储氢体系，然后利用压力–组成–温度（P–C–T）测试仪测试了该体系的储氢性能。同时，通过X射线衍射（XRD）方法对球磨产物及吸放氢产物的相结构进行了分析，探讨了该体系吸放氢性能改善的微观机制。 研究结果表明，LiAlH4–10%MgF2体系的储氢性能远远优于纯LiAlH4。该体系在200 oC温度下能快速放氢，很短时间内放氢过程基本完成且起始放氢温度较纯LiAlH4体系要低很多，既使在150 oC温度下，该体系也有很好的放氢效果，说明催化剂MgF2对LiAlH4有良好的催化作用。此外，机械球磨也可能对LiAlH4–10%MgF2体系的吸放氢有很大的促进作用，加速了LiAlH4的分解。 关键词：储氢材料；LiAlH4；球磨；储氢性能 The effect of metal fluoride on the hydrogen de-/absorption properties and mechanism of LiAlH4 Abstract It is well known that the hydrogen storage technology is the most critical aspect in the whole system of the application of hydrogen energy. Therefore, the development of high-performance hydrogen storage materials is a premise for the safe and efficient application of hydrogen energy. In this thesis, the LiAlH4–10% MgF2 hydrogen storage system was prepared by ball milling. Then its hydrogen storage property was tested by a Pressure–Composition–Temperature (P–C–T) apparatus. Meanwhile, the phase component of the ball-milled and de-/hydrogenated products was analyzed by X-ray diffraction (XRD). Finally, the mechanism contributing to the improvement of the hydrogen storage property was discussed. The results show that the LiAlH4–10% MgF2 system has an improved hydrogen storage property as compared with pure LiAlH4. The LiAlH4–10% MgF2 system can rapidly release hydrogen at the temperature of 200 oC, the progress of released hydrogen was completed in a very short time and the lowest temperature of hydrogen release is much lower than pure LiAlH4. The system also has a very perfected hydrogen storage property at 150 oC, indicating that MgF2 act as a good catalyst for LiAlH4. In addition, ball milling maybe has a great impact on the hydrogen storage property of the LiAlH4–10% MgF2 system, it can promote and accelerate the decomposition of LiAlH4 possibly. Key Words：Hydrogen storage material; LiAlH4; Ball milling; Hydrogen storage proper