鄱阳湖沉积物中磷的赋存形态及分布特征.docVIP

J.Lake Sci.(湖泊科学,2010,22(5:649-654 htt p://.E-m a i:l jlakes@nig l 2010by J ournal of Lake Sciences 鄱阳湖沉积物中磷的赋存形态及分布特征* 向速林1,2,周文斌1 (1:南昌大学教育部鄱阳湖湖泊生态与生物资源利用重点实验室,南昌330047 (2:华东交通大学环境工程系,南昌330013 摘 要:利用分级提取法对鄱阳湖沉积物进行了磷形态的分级提取和测定,系统研究了沉积物中磷的赋存形态及分布特征.结果表明,鄱阳湖表层沉积物中磷的赋存形态主要包括铁磷(Fe-P、钙磷(C a-P、铝磷(A-l P、可溶性磷(DP等无机磷(IP及有机磷(OP,各形态磷的空间分布基本具有从河口地区监测点向湖区监测点方向升高的趋势,垂向分布上总磷及各形态磷含量随深度增加而降低.表层沉积物(0-2c m中总磷含量为578.36-813.55m g/kg,主要由无机磷组成,无机磷中以Fe-P含量最高,最大值达350.24mg/kg,占总磷的40%以上,Ca-P、A-l P含量相当,约占总磷含量的20%左右,而以DP的含量最低,含量在5%以下.有机磷含量约占总磷含量的15%左右.另外,沉积物中TP含量与Fe-P、A-l P、C a-P及OP 均具有较好的相关性,且OP含量与Fe-P、A-l P也具有较好的正相关关系,而与C a-P的相关性较弱. 关键词:沉积物;磷;赋存形态;分布特征;鄱阳湖 Phosphorus existi n g for m s and distributi o n characteristic in Lake Poyang sedi m ents X IANG Sulin1,2ZHOU W enbin1 (1:Key Laboratory o f Lake Poyang Eco l ogy and B i ores ource U tili zati on o fM OE,Nanchang U niversity,Nanchang330047, P.R.Ch i na (2:D epart m e n t of Environm en t Engi n eeri ng,East C h i na J i aotong U n i versity,N an c h an g330013,P.R.C hina Abstrac:t For m s and d i s tri buti on characteri sti cs of phosphoru s i n Lake Poyang sed i m en ts w ere st ud ied s yste m aticall y u si ng t he class ificati on extraction m et hod s for extracti ng various f or m s of ph osphoru s.The res u lts s h o w ed t hat phos phorus i n s u rface s edi m en ts m ai n l y cons ist ed of i norgan i c phos phorous s p eci es,i nvol vi ng Fe-P,Ca-P,A-l P,DP and organ ic phos phorou s species.The s pati al d i s tri buti on of phos phorus species i n s u rface sed i m ents had depressed trend fro m t h e orientation ofLak e Poyang t o t he d irecti on of ri ver i nto en tran ce of l ake(Longkou,K angshan,and t h e con tent of total ph osphoru s and phosphor u s t ypes in t h e sed i m entw ere obv i ou sl y decreas ed w it h depth.The con tent of TP of surface s ed i m en t(0-2c mrange from578.36to813.55m g/kg,and I P w as t he m aj or phos phorus s peci es i n t he s edi m en t.Fe-P w as the do m i nan t f or m of IP,w h i ch