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Chapt. 3 Polymer Solutions;3.1 Criteria (判据) of Polymer Solubility;2. Huggin’s Enthalpy of mixing;3.2 Thermodynamics of Polymer Solutions ;Flory-Huggins theory (Lattice Model (格子模型));;Entropy of mixing from FH theory;Free Energy of FH Theory;Chemical potentials (化学位):;Osmotic pressure (渗透压):;Appendix: Osmotic pressure;Polymer Shapes in Dilute Solutions;3.3 Chain Conformations in Dilute Solutions;溶液中真实单链的末端距概率分布函数W(h,x);1. Polymer chain in good solvents –method I;2. Polymer chain in good solvents - method II;How to get ideal chain?;When does the freely jointed chain works－等效自由连接链;3. Polymer chain in poor solvents-Method I;3. Polymer chain in poor solvents-Method II;Polymer Shapes in Dilute Solutions;3.4 Semi-dilute Solutions of Polymers; overlap concentration c*;Scaling Law of semi-dilute solution;;Polymer Shapes in Semi-dilute Solutions;;3.5 Concentrated Solutions of Polymers;Flory-Huggins free energy of a gel;Basic Equation of Gel Swelling ;Volume Phase Transition of Gels;3.6 Solutions of Polyelectrolytes ;3.7 Thermodynamics of Polymer Mixtures;The Phase Behavior of Polymer Mixtures;Phase Diagram and Phase Equilibrium;How to calculate the phase diagram from free energy ? ;Finding the phase equilibrium conditions;;(1) Phase equilibrium curve – binodal ;(2) Metastable/unstable limits - spinodal;(3) Critical point;;UCST/LCST; Why UCST or LCST;Phase Equilibrium;Phase Separation Dynamics;Phase diagram and phase separation mechanisms;Phase Separation Mechanisms;Phase Separation Mechanisms;Examples of Phase Separation Dynamics;3.8 Theromodynamics of Block Copolymers;Self-assembly of Diblock Copolymers;Microphase Separation of Diblock Copolymers (BCPs);Microphase Separation of Triblock Copolymers;Thermodynamics of Microphase Separation;entropic spring term;Appendix;c - the key parameter in polymer physics;3.9 Hydrodynamics of Polymer Solutions;Instrinsic viscosity (特性粘数) ;[h] dependence of MW: Flory-Fox equation
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