探究三种交联剂对改性磁性壳聚糖吸附的影响.docxVIP

探究三种交联剂对改性磁性壳聚糖吸附剂的影响 摘要 磁性壳聚糖纳米粒子兼具壳聚糖的生物相容性、可降解性与磁性粒子的磁响应性，因而受到人们的广泛关注。但是磁性壳聚糖纳米粒子不成形状，本文使用环氧氯丙烷、戊二醛和三聚磷酸钠与磁性壳聚糖发生交联反应，制备出三种交联剂改性的球状磁性壳聚糖，且产率大都高于85%o并研究、比较了它们的吸附性能，三种吸附剂的吸附过程均符合准二级动力学模型。在相同情况下，三聚磷酸钠改性磁性壳聚糖的吸附速率快、吸附容量高（最大吸附容量为166.99 mg/g）o同时使用FTIR、XRD、TGA和SEM表征这些材料，FTIR表征表明三种交联剂主要与磁性壳聚糖的羟基发生交联反应；XRD表征表明磁性壳聚糖成功附着上了铁；SEM表征表示交联磁性壳聚糖表面的大孔径有利于对UO22+的吸附。这些特点突出了改性壳聚糖对处理UCh2+污染的水的适用性。本文中制备的新型吸附剂对含UO22+废水有显著作用，为制备新的吸附铀材料奠定试验和理论基础，推动了我国核电事业的发展，对环境保护、资源综合利用等领域做出突出贡献。然而，三聚磷酸钠与壳聚糖溶液的相容性不是很高，这对制备三聚磷酸钠改性磁性壳聚糖的产率产生了一定影响。 关键词：磁性壳聚糖；铀吸附；环氧氯丙烷；戊二醛；三聚磷酸钠 ABSTRACT Magnetic chitosan nanoparticles have received extensive attention, because of thebiocompatible and biodegradable of chitosan and the magnetic responsiveness of magneticnanoparticles. However, there are many problems about the performance of the magneticchitosan. In this study, epichlorohydrin, glutaric dialdehyde and tripolyphosphate are usedas cross-linking agent to modify the magnetic nanoparticles, and the yields of this threemodified magnetic chitosan are about 85%. Their adsorption capacities are disscuss in thistext. Under the same situation, tripolyphosphate-crosselinked magnetic chitosan have a fastadsorption rate and high adsorption capacity(The maxmum adsorption capacity is 166.99mg/g). The adsorption mechanism could be better described by the pseudo-second-orderequation. The chemical structure and the percentage content of each element of chitosanderivatives were characterized by infrared spectroscopy, solid state X-ray diffractionanalysis, thermogravimetric analysis and transmission electron microscope, respectively.The FTIR spectra of the modified magnetic chitosan indicates that magnetic chitosan werereacted with hydroxy. The XRD patterns shows that iron had adhered to chitosansuccessfully. The SEM image of the modified magnetic chitosan displays that the surfacetexture is favorable for adsorbing UO22+. These features highlight the suitability ofmodified magnetic chitosan for the trea