UOP 965-2010 国外国际标准.pdfVIP

Total Cycloparaffins and Total Aromatics in Synthetic Paraffinic Kerosene Fuels by Comprehensive Two-Dimensional GC with Flame Ionization Detection UOP Method 965-10 Scope This method is for determining total cycloparaffins (naphthenes) and total aromatics in synthetic paraffinic kerosene fuels (SPK) or petroleum distillates in the boiling range of 69˚C to 350˚C using comprehensive two-dimensional gas chromatography (GCxGC) coupled with a flame ionization detector (FID). Molecular type groups are identified by their location, as plotted on a chromatographic contour plot image. The precision of this test method has been established for SPK fuels containing from 1.6 to 32.3 mass-% naphthenic hydrocarbons and 0.03 to 1.9 mass-% aromatic hydrocarbons. Alkenes and compounds containing sulfur, nitrogen, and oxygen are possible interferents. References UOP Method 999, “Precision Statements in UOP Methods,” Zoex GC Image Users’ Guide, Zoex Technical Note KT030606-1: “What is Loop Modulation?” Outline of Method The sample to be analyzed is injected into a gas chromatograph that is equipped with a two-stage thermal modulator system, “primary” and “secondary” fused silica capillary GC columns and a flame ionization detector (FID). The modulator serves as an interface between the two GC columns. The first “primary” column is a conventional high resolution capillary GC column coated with cross- linked methyl silicone stationary phase, which separates molecules based on volatility. The “secondary” GC column is coated with cross-linked polyethylene glycol; it is short and narrow, for fast GC separations based on the molecular property of polarity. The modulator repetitively accumulates, focuses and re-injects “heart-cut” fractions eluting off the “primary” column onto the “secondar