!苯酚废水处理的试验研究.doc

农业环境科学学报2005,24(增刊:158-160 J ournal of A gro-Env iron m ent Science 苯酚废水处理的试验研究 程爱华1,2,李 杰1,3,王亚娥3 (1.西安建筑科技大学环境与市政学院,陕西西安 710055;2.西安科技大学地质与环境工程系,陕西西安 710054; 3.兰州交通大学环境科学与环境工程学院,甘肃兰州 730071 摘要:通过试验对比了活性炭吸附法、电解法、活性炭填充电极电解法处理苯酚废水的效果,探讨了其反应机理。在对影响处理苯酚废水去除率的各种要素如反应时间、电流密度、原水浓度、p H值等进行条件试验后,得出了去除苯酚静态试验的最佳条件。对活性炭填充电极电解法处理苯酚废水而言,电流密度、原水浓度、p H值的影响不大,最佳反应时间为60m i n,最佳N aC l投加量为0.2%。 关键词:活性炭吸附法;电解法;活性炭填充电极电解法;酚;静态试验 中图分类号:X703.1文献标识码:A文章编号:1672-2043(2005增刊-0158-03 Exper i m entalR esearch on t he Treat m ent of PhenolW aste water C HENG A i-hua1,2,L I Jie1,3,WANG Y a-e3 (1.Env iron m ental and M un i c i pal Co ll ege,X i an U n i ve rsity o f A rch itecture and T echno logy,X ian710055,Chi na;2.D ept. o f G eology and Env iron m enta l Eng i neeri ng,X i an U n i versity of Sc i ence and T echno logy,X i an710054,Ch i na;3.Co ll ege o f Env iron m ental Science and Eng ineer i ng,L anz hou Ji ao t ong U n i ve rs i ty,L anzhou730071,Ch i na Abstrac t:Pheno,l as a k i nd o f po ison,ex ists i n m any che m i ca l and phar m aceutica,l pe troche m i ca l i ndustrial and re lated i n dustr i es.T he re f o re the remova l of pheno lw aste w ater is o f env iron m ental i nte rest.The remova l of pheno l i n w aste w ater by t he acti vated carbon,the electro l ys i s and the electro l ysis o f ac ti vated ca rbon w ere compared.T he resu lts sho w ed t hat t he resi dence ti m e,density o f e lectr i c curren t,concen trati on o f the pheno lwastewa ter and p H a ll affec ted the decompositi on o f pheno.l Com pared w ith acti vated carbon and t he e l ec tro lysis,the e lectro l ysis o f acti v ated carbon show ed best pheno l re m ov i ng effects,due to t he j o i ned functi on of adsorption,ox i dation reducti on and cata l ys i s.T he density of e l ectric current,concentra ti on o f the phe nol wastewa ter and p H had little e ffects on the e l ec tro lysis of acti va ted carbon,wh ile the dispo si ng e ffect was g reatly affec ted by the infl uent conduc tiv ity and rea