《高分子物理》第1章链结构.ppt

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ? 持续长度（自由旋转链） S为两个结构单元间的轮廓线长度 s l 高分子链为刚性 s l 分子链失去记忆效应. ~ ~ * Advantage of lk : it can be directly experimentally measured. Advantage of : it has a direct microscopic meaning. * 1.4.7 真实链: 排斥体积 excluded volume In real polymer chain, the repeating units have occupied volume and they can not interpenetrate. (Rotation of singl