《高分子物理》第2章无定型聚合物.ppt

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * BSR Rubber丁苯橡胶-made from 1,3 butadiene * * * * * * * * * * * * * * * * * * * * * * * * * * * * 3. Effect of Pressure 压力的影响 Since an increased pressure causes a decrease in the total volume, an increase in Tg is expected based on the prediction of decreased free volume Glass transition versus pressure for various substances Kf为自由体积的等温压缩系数 ?K为Tg上下的压缩系数差 * Pressure coefficients of the glass transition temperatures for selected materials aThe variation is probably due to the different compressibilities