金燃料电池催化剂的发展前景.pptVIP

The Future of Gold As Fuel Cell Catalyst Contents Introduction Gold for anode catalyst Gold for cathode catalyst Summary References Principle of PEMFC Introduction - + H2 or MeOH H2 or CO2 Air (O2) H2O +Air (O2) H+ Catalyst support (carbon paper or cloth) Nafion? membrane Current collector / gas distributor Catalyst layer Challenges for catalyst: High cost of PGMs Kinetic loss due to insufficient activity Stability is not enough Why consider gold? Ⅰnanosized gold is very active for CO oxidation reaction M. Haruta / Catalysis Today 36 (1997) 153-166 Introduction Why consider gold? ⅡThe use of gold in conjunction with Platinum group metals (PGMs) could help to reduce the cost of fuel cell technology J. Luo et al. / Catalysis Today 292 99 (2005) 291–297 Introduction Potential application of Au as an electrocatalyst Alkaline Fuel Cells Supported Au or Au-Pt catalysts may have applications as anode and cathode electrocatalysts. Low temperature alkaline fuel cells are very susceptible to CO poisoning. Gold catalysts have been shown to be capable of oxidizing CO at similar low temperature. PEM Fuel Cells PEMFC operating on reformed gas suffer from co poisoning. Hence PEM cell anodes and cathodes could potentially benefit from the use of Au-based catalysts, exhibiting improved performance at lower cost. Direct Methanol Fuel Cells Selectivity for the oxygen reduction reaction is a prime requirement for the cathodes of direct methanol fuel cells. Au or Au-alloy catalysts offer promising selectivity and performance. And also, Au will help to improve the stability of both anode and cathode catalyst, which is very important for long time running. Introduction Main research groups in this field CJ Zhong, Suny ,USA Prepare Au or Pt-Au catalyst and investigate the MeOH electrocatalytic activity , J. Luo et al. / Catalysis Today 292 99 (2005) 291–297 Kyoto University, Japan ? ‘Methanol Oxidation on Ultra-fine gold deposited catalysts’ K. Mat