无机化学课件07 group IVA.pptxVIP

Group IV A or 14;Carbon;Graphite ;Diamond;Diamond ;Fullerenes C60 ;Smalleys apparatus for generating and detecting buckyball. ;Schematic of a mass spectrometer ;“..in the field of Observation, chance only favors the prepared mind” Louis Pasteur;C60;Fullerene; All have 12 pentagonal faces, 145.5 pm on a side. C60 has 20 hexagonal faces, 139 pmT= 5K on a side. The C=C between two pentagons is electron rich, The pentagons themselves are electron poor. The LUMO of C60 is triply degenerate. Fullerides C60-1 to –6, C603- are superconducting below T = 28K. Fullerenes may encapsu