乙苯精馏工段设计.docx

PAGE PAGE III 年产7万吨乙苯生产工艺设计 摘要：乙苯是重要的有机原料之一及中间体，主要用于生产苯乙烯，进而作为橡胶及塑料等高分子材料的单体。国内大多采用苯与乙烯烷基化的方法生产乙苯。此次设计以年产7万吨乙苯为生产目标，用无水AlCl3作为催化剂，HCl作助催化剂，通过催化络合物的配置、烷基化反应、络合物的沉淀与分离、中和除酸、粗乙苯的精制与分离等工序得到精制乙苯。根据设计要求对全部生产工艺进行物料衡算、热量衡算，并根据计算结果对苯精馏塔进行设备选型，最终采用塔径1600mm,塔高为26.68m的浮阀精馏塔。设计的重点是生产工艺设计论证、工艺设计计算及设备选型。附有工艺流程图，主要设备结构尺寸。 关键词：乙苯；烷基化；工艺设计 Production process design of ethylbenzene with an annual output of 70,000 tons Abstract：Ethylbenzene is one of the important organic raw materials and intermediates. It is mainly used for the production of styrene and then as a monomer for polymer materials such as rubber and plastics. Domestically, ethylbenzene is produced by alkylation of benzene and ethylene. The design aims to produce 70,000 tons of ethylbenzene per year, using anhydrous AlCl3 as a catalyst and HCl as a co-catalyst, through the configuration of catalytic complex, alkylation reaction, precipitation and separation of complex, and neutralization Processes such as acid removal, crude ethylbenzene purification and separation yield refined ethylbenzene. According to the design requirements, the material balance and heat balance are calculated for all production processes, and the equipment selection is performed for the benzene distillation tower according to the calculation results. Finally, a float valve distillation tower with a tower diameter of 1600 mm and a tower height of 26.68 m is used. The focus of the design is on production process design demonstration, process design calculation and equipment selection. Attached process flow chart, main equipment structure size. Key words:Ethylbenzene; alkylation; process design 目录 TOC \o 1-3 \h \u 摘要 II Abstract III 1 综述 1 1.1 前言 1 1.1.1 产品用途 1 1.1.2 设计规模和产品主要性质 1 1.1.3 气液相烷基化基本原理 2 1.1.4 选题背景 3 1.2 概述 4 1.2.1 由C8芳烃分离乙苯 4 1.2.3 国外乙苯生产现状及开发动向 5 1.2.4 国外乙苯生产现状及开发动向 6 1.3 结语 8 2 生产工艺流程设计 9 2.1 工艺参数的确定 9 2.2 物料衡算 9 2.2.1 烷基化反应器工艺流程图 9 2.2.2 物料平衡示意图 10 2.2.3 计算基准 10 2.2.4 原料乙烯进