【图文】热力学计算方法.docVIP

ΔU = ΔU1 + ΔU 2 = -240.579 kJ + 114.752(T －298.15 ×10-3 kJ = 0 ? 240.579 ? T ?? ? 298.15? K ? 2394.65K ? 2121.5 C 114.752? 10? 3 ? ? p1V ? ? nB (反应物, g RT1 ; B p V ? ? nB (产物, g RT B ? n (产物, g RT p? ? n (反应物, g RT B B B B ? p1 1 n( H 2O, g ? n(O 2 ? n( N 2 ? n( H 2 ? n(O 2 ? n( N 2 4.0714 ? 2394.65 ? ? 100kPa ? 715.3kPa 4.5714? 298.15 00-8-15 21