《药物合成反应》人名反应.docVIP

《药物合成反应》人名反应 授课教师：武汉大学药学院郭鹏教授 2010,12,20 Aldol condensation Arndt–Eistert homologation Baeyer–Villiger oxidation Beckmann rearrangement Benzilic acid rearrangement Benzoin condensation Birch reduction Buchwald–Hartwig amination Cannizzaro reaction Claisen condensation Claisen rearrangement para-Claisen rearrangement Clemmensen reduction Cope rearrangement Criegee mechanism of ozonolysis Curtius rearrangement Darzens condensation Delépine amine synthesis Demjanov rearrangement Tiffeneau–Demjanov rearrangement Dieckmann condensation Favorskii rearrangement Fries rearrangement Gabriel synthesis Gattermann–Koch reaction Hofmann rearrangement Houben?Hoesch reaction Jones oxidation Knoevenagel condensation Leuckart–Wallach reaction Mannich reaction Meerwein–Ponndorf–Verley reduction Michael addition Moffatt oxidation Nef reaction Oppenauer oxidation Paal–Knorr furan synthesis Paal–Knorr pyrrole synthesis Perkin reaction Pinacol rearrangement 基团迁移顺序：富电子基团迁移最快 烷基：3o 环己基 2 o 苄基 苯基 1 o 甲基 H 取代芳基：给电子取代的迁移能力大于无取代的芳基，无取代大于吸电子基团取代的芳基 Prévost trans-dihydroxylation Prins reaction Reformatsky reaction Reimer–Tiemann reaction Robinson annulations Robinson?Sch?pf reaction Rosenmund reduction Sandmeyer reaction Schmidt rearrangement Sommelet reaction Sommelet–Hauser rearrangement Stobbe condensation Strecker amino acid synthesis Swern oxidation Vilsmeier?Haack reaction [1,2]-Wittig rearrangement [2,3]-Wittig rearrangement Wolff rearrangement Wolff–Kishner reduction Woodward cis-dihydroxylation 有关Cr的氧化剂 极性反转