高分子材料加工技术专业英语 Structure of Macromolecular Chains 20.polymer structure.ppt

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高分子材料加工技术专业英语 Structure of Macromolecular Chains 20.polymer structure.ppt

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* * /imgres?imgurl=/wp-content/uploads/2007/11/rain.jpg&imgrefurl=/index.cfm%3Ffuseaction%3Duser.viewprofile%26friendID%3D305674480&h=338&w=506&sz=77&hl=en&start=1&um=1&tbnid=wrKsL4LcsRlcWM:&tbnh=88&tbnw=131&prev=/images%3Fq%3DRain%26um%3D1%26hl%3Den%26rls%3Dcom.microsoft:en-US /web_sample_report_files/image004.jpg * /yermie/www/images/shark%20laserbeam.jpg * /1212/907793508_fjpg * Properties Weather Resistance When it comes to weather resistance, the most damaging aspect of weathering is generally considered to be Ultraviolet light. The UV light breaks down the chains of the polymers making them more brittle, causing colors to fade or yellow, and causing additives in the polymers to migrate to the surface (chalking). * Properties Weather Resistance Amorphous polymers have better chemical resistance to weathering effects than S/C polymers. The crystals in the S/C polymers diffract the light so the UV rays spend more time within the polymer structure and do more damage. The clear amorphous polymers allow the damaging radiation to pass through doing less damage. * Properties Shrinkage Because they fold up into crystal structures, S/C materials have higher shrinkage rates when compared to Amorphous materials. In injection molding most amorphous materials will shrink between 0.003-0.007 in/in (0.3-0.7%) S/C materials shrink differently depending upon the level of crystallinity that they achieve. Some will shrink over 0.025 in/in depending on processing variables, part thickness, and additives. * Crystalline vs Amorphous Thermoplastics: Crystalline (actually usually semi-crystalline): Atomic bonds regular and repeated Have a defined melting point Tm Can contain some degree of amorphous polymer Usually translucent to opaque * Crystalline vs Amorphous Thermoplastics: Amorphous: Extensive chain branching All thermosets are amorphous Exhibit glass tranistion temperatures Tg Below Tg, polymer acts stiff and rigid Above Tg, polymer acts soft and rubbery Melt or