高分子物理浙江大学1高分子链结构.pptVIP

Structure and Property of polymer 高分结构性能 高分子结构的 占 ,, Characteristic and classification of polymer structure  11.1高分子的结构特点 Characteristics of polymer structure Polymer is composed of many structural units linked by chemical bonds The molecular weight of polymer is very high and has polydispersity W The main chains of polymer can rotate, leading to flexibility of polymer chains Due to thermal motion, the shape(conformation) of polymer chains change with time The Van der walls force among structural units is very important W Crosslinking may greatly change properties of polymers W The aggregate state of polymer may be crystalline or amorphous. The order of polymer in crystalline state is smaller than that of small molecules, but the order in amorphous state is higher than that of small molecules  1.1.2高分子的结构层次 classification of polymer structure chemical composition 近程结构 reg1oisomerism stereoisomerism 次结构 branching crosslinking 链结构 Short range structure: bonding sequence in copolymer 高 Chain structure 远程结构(二 size(molecular weight 分 次结构 d distribution) conformation(flexibility and rigidity) 子 Long range structure 结 crystalline state 构 梨集态结构次结构》me Aggregate structure structure orientation state 高次结构 textural structure  Short range structure structural unit or local chain segment is involved Long range structure entire single polymer chain is involved ggregate structure different polymer chains are involved How about double helix structure of dna?  Polymer structure is the sum of structures at different levels, which contribute to apparent polymer properties Polymer structures at different levels are different but correlated!!! stereo-regularit crystallizability, etc conformation: liquid crystal: etc sequence of comonomer phase separation; crystallizability; etc molecular weight miscibility, et  Regulation and improvement of polymer properties can be approached by change of polymer structures at different