新型石墨烯超高分子量聚乙烯纳米复合材料讲义.docx

x. i. g/10.1021/m 301376q | c m ec e 2012, 45, 6878-6887 x. i. g/10.1021/m 301376q | c m ec e 2012, 45, 6878-6887 x. i. g/10.1021/m 301376q | c m ec e 2012, 45, 6878-6887 x. i. g/10.1021/m 301376q | c m ec e 2012, 45, 6878-6887 pubs.acs.org/Macromolecules Novel Graphene UHMWPE Nanocomposites Prepared by Polymerization Filling Using Single-Site Catalysts Supported on Functionalized Graphene Nanosheet Dispersions ? rzel,*? Fabia n Kempe Yi Thoma nr?Stefa n MarRMarkus En ders, *,? Freiburg Materials Research Center (FMF) and Institute for Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. ?31, D-79098 Freiburg, Germany Anorganisch-Chemisches Institut, University of Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany ABSTRACT: Novel families of ultrahigh-molecular-weight polyethylene (UHMWPE) nano composites, containing un iformly dispersed, fun cti on alized graphe ne (FG) nano sheets, were prepared by means of the polymerizati on ?lli ng tech ni que (PFT). Un paralleled by any other carb on and boehmite nano composites, fG/UHMWPE exhibited an un usual simulta neous improveme nt in stffn ess, elon gati on at break, and effective nucleation of polyethylene crystallization at only 1 wt % FG content. FG nano sheets are ultrathi nwith a thick ness of only one carb on atom and lateral dime nsions of several micrometers. Owi ng to the prese nce of surface hydroxyl groups on the FG, sin gle FG/methylalumi noxane (MAO) nano sheets can be effectively dispersed in n-heptane, thus enabling immobilization of an MAO-activated chromium (Cr1) single-site catalyst on FG. In con trast to nano meter-scale carb on black (CB), multiwall carb on nano tubes (CNT), graphite, and nano boehmite, which failed to form stable dispersions, FG/MA0/Cr1 afforded the highest catalyst activities and excellent morphological control. In yme iz i ? i g, e i eg i ic e i e i i e yme iz i ce e imi e e ee pecial safety and han dli ng precauti ons typically required by conven ti