Roel-Prins-昌平-石油大学-加氢脱硫脱氮机理.pptVIP

Elimination or Substitution a) Elimination b) Substitution SN2 β-H α-C N. Nelson, R.B. Levy, J. Catal. 58 (1979) 485 Hydrogenation of aromatic ring Removal of N atom Elimination or Substitution 1. Hofmann β-H elimination J.L. Portefaix et al. Catal. Lett. 9 (1991) 127 2. Nucleophilic substitution L. Vivier et al. J. Mol. Catal. 67 (1991) 267 HDN Network of Pentylamine N H 2 S H N H H 2 S H 2 S Y. Zhao, P. Kukula, R. Prins, J. Catal. 221 (2004) 441 NH2-SH substitution via imine intermediate R. Prins, Y. Zhao, N. Sivasankar, P. Kukula, J. Catal. 234 (2005) 509 HDO HydroDe-Oxygenation H