生物化学之多糖分析.pptVIP

1.2寡糖和多糖 oligosaccharides and polysaccharides 6CH.OH Axis m CHoO a OH H er-D-Gluco g-p-Fructofuranose Two possible chair forms CHOO AXs OH H CH,OH 户 D-Glucopyranose 户 n-Fructofuranose r-D-Glucopyranose FIGURE 7-8 Conformational formulas of pyranoses. (a) Two chair forms of the pyranose ring. Substituents on the ring carbons may be either axial (ax), projecting parallel to the vertical axis through the ing, or equatorial (eq, projecting roughly perpendicular to this axis. Pyran Two conformers such are these are not readily interconvertible with- out breaking the ring. However, when the molecu