金属-无机配位体配合物的稳定常数.docxVIP

F表中除特别说明外均是在25C下，离子强度I =0 金属-无机配位体配合物的稳定常数 Stability Con sta nts of Metal Ion-I norganic Coord in ati on Compo unds 序号 (No.) 配位体 (Ligand) 金属离子 (Metal ion) 配位体数目n (Number of ligand) lg 3 n 1 NH Ag+ 1,2 3.24,7.05 Au3+ 4 10.3 Cd2+ 123,4,5,6 2.65,4.75,6.19,7.12,6.80,5.14 Co2+ 123,4,5,6 2.11,3.74,4.79,5.55,5.73,5.11 Co3+ 1,2,3,4,5,6 6.7,14.0,20.1,25.7,30.8,35.2 Cu+ 1,2 5.93,10.86 Cu2+ 1,2,3,4,5 4.31,7.98,11.02,13.32,12.86 Fe 1,2 1.4,2.2 Hg2+ 1,2,3,4 8.8,17.5,18.5,19.28 MrT 1,2 0.8,1.3 Ni2+ 1,2,3,4,5,6 2.80,5.04,6.77,7.96,8.71,8.74 Pd2+ 1,2,3,4 9.6,18.5,26.0,32.8 Pt2+ 6 35.3 Zn2+ 1,2,3,4 2.37,4.81,7.31,9.46 2 Br- Ag+ 1,2,3,4 4.38,7.33,8.00,8.73 Bi3+ 1,2,3,4,5,6 2.37,4.20,5.90,7.30,8.20,8.30 Cd2+ 1,2,3,4 1.75,2.34,3.32,3.70, Ce3+ 1 0.42 Cu+ 2 5.89 Cu2+ 1 0.30 Hg2+ 1,2,3,4 9.05,17.32,19.74,21.00 In3+ 1,2 1.30,1.88 Pb2+ 1,2,3,4 1.77,2.60,3.00,2.30 Pd2+ 1,2,3,4 5.17,9.42,12.70,14.90 Rh3+ 2,3,4,5,6 14.3,16.3,17.6,18.4,17.2 Sc3+ 1,2 2.08,3.08 Sn2+ 1,2,3 1.11,1.81,1.46  Tl 3+ 123,4,5,6 9.7,16.6,21.2,23.9,29.2,31.6 U4+ 1 0.18 y3+ 1 1.32 3 Cl- Ag+ 1,2,4 3.04,5.04,5.30 Bi3+ 1,2,3,4 2.44,4.7,5.0,5.6 Cd2+ 1,2,3,4 1.95,2.50,2.60,2.80 Co3+ 1 1.42 Cu+ 2,3 5.5,5.7 Cu2+ 1,2 0.1, -0.6 Fe2+ 1 1.17 Fe 2 9.8 2+ Hg 1,2,3,4 6.74,13.22,14.07,15.07 In 3+ 1,2,3,4 1.62,2.44,1.70,1.60 Pb2+ 1,2,3 1.42,2.23,3.23 Pd2+ 1,2,3,4 6.1,10.7,13.1,15.7 Pt2+ 2,3,4 11.5,14.5,16.0 Sb3+ 1,2,3,4 2.26,3.49,4.18,4.72 Sn2+ 1,2,3,4 1.51,2.24,2.03,1.48 Tl3+ 1,2,3,4 8.14,13.60,15.78,18.00 Th4+ 1,2 1.38,0.38 Zn 1,2,3,4 0.43,0.61,0.53,0.20 Zr4+ 1,2,3,4 0.9,1.3,1.5,1.2 4 CN Ag+ 2,3,4 21.1,21.7,20.6 Au+ 2 38.3 Cd2+ 1,2,3,4 5.48,10.60,15.23,18.78 Cu+ 2,3,4 24.0,28.59,30.30 Fe 6 35.0 Fe 6 42.0 时 4 41.4 Ni2+ 4 31.3 Zn2+ 1,2,3,4 5.3,11.70,16.70,21.60 5 F Al3+ 1,2,3,4,5,6 6.11,11.12,15.00,18.00,19.40,19.80 Be2+ 1,2,3,4 4.99,8.80,11.60,13.10  Bi3+ 1 1.42 Co2+ 1 0.4 Cr3+ 1,2,3 4.36,8.70,11.20 Cu2+ 1 0.9 Fe 1 0.8 Fe3+ 1,2,3,5 5.28,9.30,12.06,15.77 GaT 1,2,3 4.49,8.00,10.50 Hf4+ 123,4,5,6 9.0,16.5,23.1,28.8,34.0,38.0 Hg2+ 1 1.03 In