文版107提供第六次课10 reaction rate theories.pptVIP

c) Glancing collisions: Its line-of-centers energy available for chemistry is zero, and any “collision” with bd also has no contribution to : The line-of-centers energy just matches the energy barrier at an impact parameter. For a given energy, every collision with impact parameter less than bmax has , and reaction can occur. The total reactive cross section at energy is: If the collision is less than : The mass-action kinetics expression for the reaction rate: From the line-of-centers results, the integral is: Th