无污染水性涂料 .docxVIP

工程建筑学相关资料ENGINEERING ARCHITECTURE RELATED INFORMATION 工程建筑学相关资料 ENGINEERING ARCHITECTURE RELATED INFORMATION PAGE PAGE 1 无污染水性涂料  　　论文关键词：丙烯稀丁酯　苯乙烯　乳液聚合　预乳液　乳化剂　引发剂 　　论文摘要 ：本文叙述了，苯乙烯和丙烯酸丁酯在乳化剂：十二烷基硫酸钠，引发剂：过硫酸铵，存在的情况下利用连续滴加预乳液的聚合工艺，合成苯丙乳液的过程。并通过几组平行实验确定反应温度、搅拌速度、预乳液的滴速及不同时期反应时间对乳液合成及其性能的影响。通过观察反应现象及利用测定实验产物的数据，不断对实验进行改进，尽量减小不良因素对产物性能的影响。试验表明：　　温度在82-84℃，预乳液在两小时左右滴完，预乳液发生聚合的现象明显。温度50℃，强力搅拌一小时制得的预乳液的质量较好。引发剂的量应小于0.3%，用量过大乳液会发生破乳。　　Abstract ：This text has been narrated， styrene and acrylic acid cube ester are in the emulsifier : 12 alkyl sulphuric acid sodium， initiator: Pass sulphuric acid ammonium ， is it is it add craft of getting together of the cream in advance to drip in succession to utilize under the situation that exist， formate the course of third cream of benzene. And parallel experiment confirm temperature of reacting ， mix speed， cream drip speed and react time impact on the cream is formated and performance with period in advance through several group. Through observing the phenomenon of reacting and utilizing determining the data which test the result ， are improving the experiment constantly， try ones best to reduce the impact on performance of the result of the bad factor. The test shows : 　　Temperature， in 82-84 degrees Centigrade， the cream is dripped in about two hours in advance， the phenomenon that the cream gets together is obvious in advance. 50 of temperature， brute force mix make one hour the quality of the cream is better in advance. The quantity of the initiator should be smaller than 0.3%， the broken milk happens in the too big cream of consumption .　　Keywords: Propylene rare cube ester Styrene The cream getting together The cream in advance Emulsifier Initiator 　　第一章 绪论 　　建筑涂料的发展方向是无毒安全、节约资源、有利于环境保护的水性涂料和无公害低污染涂料。不断提高水性涂料的质量，开发新的品种，是巩固和发展水性建筑涂料的重要环节之一。　　国外对建筑物的外墙面装饰非常重视，，经常有计划地涂装建筑物外墙，有的国家高达90％。在我国，相当一部分建筑仍然采用面砖或幕墙进行装饰，而用涂料进行装饰的还不足10％。目前使用的外墙涂料品种主要为乳胶涂料和溶剂型涂料，前者大多为苯丙、纯丙薄质乳胶涂料及厚质复层涂料；后者使用较少，但随着最近推出的低毒溶剂型丙烯酸涂料的出现，使用量有所增加